Journal ArticleDOI
Effect of lithium ion content on the lithium ion conductivity of the garnet-like structure Li 5+x BaLa 2 Ta 2 O 11.5+0.5x ( x = 0–2)
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In this article, a systematic study on the transport properties by varying the lithium oxide content of the garnet-based solid electrolyte Li5+xBaLa2Ta2O2O11.Abstract:
We report systematic studies on the transport properties by varying the lithium oxide content of the garnet-based solid electrolyte Li5+xBaLa2Ta2O11.5+0.5x (x=0, 0.50, 0.75, 1.00, 1.25, 1.50, 1.75, 2.00) for understanding the ionic conductivity dependence on the crystal lattice parameter and carrier concentration. Powder X-ray diffraction data of Li5+xBaLa2Ta2O11.5+0.5x (x=0, 0.50, 0.75, 1.00, 1.25, 1.50, 1.75, 2.00) indicate the existence of the garnet-like structure for any of the compositions. The cubic lattice parameter was found to increase with increasing x and reaches a maximum at x=1.00, then decreases slightly with a further increase in x. Impedance measurements obtained at 50 °C indicate a maximum of the grain-boundary resistance (Rgb) contribution to the total resistance (Rb+Rgb) at x=0.0 and a considerable decrease with increase in lithium concentration. The total (bulk + grain-boundary) and bulk ionic conductivity increase with increasing lithium content and reach a maximum at x=1.00 and then decrease slightly with further increase in x. Among the investigated compounds, Li6BaLa2Ta2O12 exhibits the highest total (bulk + grain-boundary) and bulk ionic conductivity of 1.5×10-4 and 1.8×10-4 S/cm at 50 °C, respectively. The results obtained in the present investigation of the Li5+xBaLa2Ta2O11.5+0.5x (x=0–2) series clearly revealed that the lithium content plays a major role in decreasing the grain boundary resistance contribution to the total resistance and also in increasing the ionic conductivity of the garnet-like compound.read more
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Journal ArticleDOI
High ionic conductivity in lithium lanthanum titanate
Yoshiyuki Inaguma,Chen Liquan,Mitsuru Itoh,Tetsurō Nakamura,Takashi Uchida,Hiromasa Ikuta,Masataka Wakihara +6 more
TL;DR: In this paper, the polycrystalline lithium lanthanum titanate Li0.34(1)La0.5O4.94(2) showed high ionic conductivity more than 2 × 10−5 S cm−1 (D.C.A.
Journal ArticleDOI
Novel Fast Lithium Ion Conduction in Garnet-Type Li5La3M2O12 (M = Nb, Ta)
TL;DR: In this paper, Li5La3M2O12 (M = Nb, Ta), possessing a garnet-like structure, has been investigated with regard to their electrical properties.