Effect of the Addition of α-Si3N4 on the Direct Nitridation of Silicon Powder at Atmospheric Pressure

TLDR: In this article, the effect of adding α-Si3N4 diluent on the nitridation of silicon powder was studied at 1550 and atmospheric pressure, and the results showed that the conversion of silicon is improved considerably by increasing the adding proportion of αSi3 N4 dilument, and that the sinterability of silicon nitride decreases as the content of β phase increases.

Abstract: Effect of the addition of α-Si3N4 on the nitridation of silicon powder was studied at 1550 and atmospheric pressure. Silicon powder of 2.2μm in size and 99.99% in purity was adopted as experimental materials, α-Si3N4 powder of 2.2μm in size and 99% in purity was used as diluent, and nitrogen of 99.9993% in purity was used as reaction gas. The morphologies and phase compositions of the products were analyzed by SEM and XRD respectively. The results show that the conversion of silicon is improved considerably by increasing the adding proportion of α-Si3N4 diluent. When the adding proportion of α-Si3N4 increases from 10% to 50%, the conversion of silicon powder increases from 38% to 92.55%. The content of β-Si3N4 in product decreases, after an initial increase, with the adding proportion of α-Si3N4 increases, and it reaches the peak point when the adding proportion of α-Si3N4 was 30%. The sinterability of silicon nitride decreases as the content of β phase increases, so the adding proportion of α-Si3N4 should be kept away from 30%.