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Electronic and Defective Engineering of Electrospun CaMnO3 Nanotubes for Enhanced Oxygen Electrocatalysis in Rechargeable Zinc–Air Batteries

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This article is published in Advanced Energy Materials.The article was published on 2018-08-01. It has received 203 citations till now. The article focuses on the topics: Zinc.

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Defect Engineering on Electrode Materials for Rechargeable Batteries.

TL;DR: Recent advances regarding defect engineering in electrode materials for rechargeable batteries are systematically summarized, with a special focus on the application of metal-ion batteries, lithium-sulfur batteries, and metal-air batteries.
Journal ArticleDOI

Generation of Nanoparticle, Atomic-Cluster, and Single-Atom Cobalt Catalysts from Zeolitic Imidazole Frameworks by Spatial Isolation and Their Use in Zinc-Air Batteries

TL;DR: The spatial isolation of cobalt species on the atomic scale is reported by tuning the zinc dopant content in predesigned bimetallic Zn/Co zeolitic imidazole frameworks (ZnCo-ZIFs), which led to the synthesis of nanoparticles, atomic clusters, and single atoms of Co catalysts on N-doped porous carbon.
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Macroscopic Spontaneous Polarization and Surface Oxygen Vacancies Collaboratively Boosting CO2 Photoreduction on BiOIO3 Single Crystals

TL;DR: The synchronous promotion of bulk and surface separation of photoinduced charges for prominent CO2 photoreduction by coupling macroscopic spontaneous polarization and surface oxygen vacancies of BiOIO3 single crystals is reported.
Journal ArticleDOI

Atomically Transition Metals on Self-Supported Porous Carbon Flake Arrays as Binder-Free Air Cathode for Wearable Zinc-Air Batteries.

TL;DR: A facile and easily scalable "impregnation-carbonization-acidification" strategy for fabricating a class of single-atom-anchored monolith as superior binder-free electrocatalysts for developing high-performance wearable Zn-air batteries is reported.
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Role of Sulfur Vacancies and Undercoordinated Mo Regions in MoS2 Nanosheets toward the Evolution of Hydrogen.

TL;DR: This work explored the HER activity from defective multilayered MoS2 over a large range of surface S vacancy concentrations up to 90% and provides guidance for the development of defect-engineered TMD-based electrocatalysts.
References
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Journal ArticleDOI

Electrocatalysis for the oxygen evolution reaction: recent development and future perspectives

TL;DR: This review acquaints some materials for performing OER activity, in which the metal oxide materials build the basis of OER mechanism while non-oxide materials exhibit greatly promising performance toward overall water-splitting.
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Hollow Micro-/Nanostructures: Synthesis and Applications**

TL;DR: Hollow micro-/nanostructures are of great interest in many current and emerging areas of technology as discussed by the authors, and a comprehensive overview of synthetic strategies for hollow structures is presented.
PatentDOI

Metal-free bifunctional electrocatalyst for oxygen reduction and oxygen evolution reactions

TL;DR: A mesoporous carbon foam co-doped with nitrogen and phosphorus that has a large surface area and good electrocatalytic properties for both ORR and OER and is tested as an air electrode for primary and rechargeable Zn-air batteries.
Journal ArticleDOI

Design principles for oxygen-reduction activity on perovskite oxide catalysts for fuel cells and metal–air batteries

TL;DR: These findings reflect the critical influences of the σ orbital and metal-oxygen covalency on the competition between O(2)(2-)/OH(-) displacement and OH(-) regeneration on surface transition-metal ions as the rate-limiting steps of the ORR, and highlight the importance of electronic structure in controlling oxide catalytic activity.
Journal ArticleDOI

Toward the rational design of non-precious transition metal oxides for oxygen electrocatalysis

TL;DR: In this article, the state-of-the-art understanding of non-precious transition metal oxides that catalyze the oxygen reduction and evolution reactions is discussed, with an outlook on the opportunities in future research within this rapidly developing field.
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