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Exploring metal organic frameworks for energy storage in batteries and supercapacitors

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TLDR
In this paper, the authors review and comment on recent progress in metal-organic framework-based lithium-ion batteries, sodium-ion battery, lithium-air battery, and supercapacitors.
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This article is published in Materials Today.The article was published on 2017-05-01 and is currently open access. It has received 358 citations till now. The article focuses on the topics: Electrochemical energy conversion & Supercapacitor.

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Synthesis of γ-MnS/nanoporous carbon/reduced graphene oxide composites for high-performance supercapacitor

TL;DR: In this paper , nanoporous carbon (NPC) was prepared from a metal-organic framework (zeolite imidazolate framework 8, ZIF-8) and different concentrations of graphene oxide (GO) were used to make NPC/reduced graphene oxide composites, and then γ-MnS/NPC/rGO-1 composite was synthesized via simple hydrothermal technique.
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Riveting the atomically distributed lithiophilic centers in the CNT-reinforced interfacial layer: an ultrathin, light-weight deposition substrate toward superior Li utilization

TL;DR: In this article, an ultrathin interfacial layer of atomic Zn-doped Ndoped carbon was prepared by a stepwise pyrolysis process and is proposed to regulate the reversible metallic plating/stripping process toward Cu foil.
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Fabrication and deployment of nanodisc ZnO@ZIF-8, ZnO@NA and ZnO@INA core–shell MOFs: enhanced NH3 and HCHO gas sensing

TL;DR: In this paper, three nanodisc ZnO@MOFs with structural building units 2-methylimidazole, nicotinic acid and isotonic acid are synthesized.
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Aqueous Organic Zinc-Ion Hybrid Supercapacitors Prepared by 3D Vertically Aligned Graphene-Polydopamine Composite Electrode

TL;DR: In this paper , a three-dimensional vertical-aligned graphene-polydopamine electrode (PDA@3DVAG) composite with vertical channels and conductive network is prepared by a method of unidirectional freezing and subsequent self-polymerization.
References
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Journal ArticleDOI

Challenges for Rechargeable Li Batteries

TL;DR: In this paper, the authors reviewed the challenges for further development of Li rechargeable batteries for electric vehicles and proposed a nonflammable electrolyte with either a larger window between its lowest unoccupied molecular orbital and highest occupied molecular orbital (HOMO) or a constituent that can develop rapidly a solid/ electrolyte-interface (SEI) layer to prevent plating of Li on a carbon anode during a fast charge of the battery.
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Selective gas adsorption and separation in metal–organic frameworks

TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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The Li-ion rechargeable battery: a perspective.

TL;DR: New strategies are needed for batteries that go beyond powering hand-held devices, such as using electrode hosts with two-electron redox centers; replacing the cathode hosts by materials that undergo displacement reactions; and developing a Li(+) solid electrolyte separator membrane that allows an organic and aqueous liquid electrolyte on the anode and cathode sides, respectively.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage

TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
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Challenges in the development of advanced Li-ion batteries: a review

TL;DR: Li-ion battery technology has become very important in recent years as these batteries show great promise as power sources that can lead us to the electric vehicle (EV) revolution as mentioned in this paper.
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