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Fabrication of highly conductive Ti1- xNbxO2 polycrystalline films on glass substrates via crystallization of amorphous phase grown by pulsed laser deposition

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TLDR
In this article, Nb-doped anatase TiO2 [Ti0.94Nb0.06O2 (TNO)] films with high electrical conductivity and transparency were fabricated on nonalkali glass using pulsed laser deposition and subsequent annealing in a H2 atmosphere.
Abstract
Nb-doped anatase TiO2 [Ti0.94Nb0.06O2 (TNO)] films with high electrical conductivity and transparency were fabricated on nonalkali glass using pulsed laser deposition and subsequent annealing in a H2 atmosphere. The amorphous films as deposited on unheated substrates were found to crystallize, forming polycrystalline films at around 350°C. The films annealed at 500°C showed resistivity down to 4.6×10−4Ωcm at room temperature and optical transmittance of 60%–80% in the visible region, which are comparable to those of epitaxial films. These results indicate that TNO films have the potential to be practical transparent conducting oxides that could replace indium tin oxide.

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Citations
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Journal ArticleDOI

Solution processing of transparent conductors: from flask to film

TL;DR: This critical review focuses on the solution deposition of transparent conductors with a particular focus on transparent conducting oxide (TCO) thin-films, with an introduction into the applications of and material criteria for TCOs.
Journal ArticleDOI

n-Type doped transparent conducting binary oxides: an overview

TL;DR: In this article, the authors provide an accessible tutorial of the physical descriptions of transparent conducting oxides, and an up-to-date overview of the field, with a brief history, some key accomplishments from the past few decades, the current state of the research, as well as postulation on some likely future developments.
Journal ArticleDOI

Properties of TiO2‐based transparent conducting oxides

TL;DR: In this paper, the development and properties of titanium dioxide (TiO 2 )-based transparent conducting oxides (TCO), which exhibit properties comparable to those of In 2-x Sn x O 3 (ITO), are reviewed.
Journal ArticleDOI

Niobium-doped titania nanoparticles: synthesis and assembly into mesoporous films and electrical conductivity.

TL;DR: Crystalline niobium-doped titania nanoparticles were synthesized via solvothermal procedures using tert-butyl alcohol as a novel reaction medium, and their assembly into mesoporous films was investigated.
References
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Journal ArticleDOI

Transparent Conducting Oxides

David S. Ginley, +1 more
- 01 Aug 2000 - 
TL;DR: In the interim between the conception of this issue of MRS Bulletin on transparent conducting oxides and its publication, remarkable applications dependent on these materials have continued to make sweeping strides.
Book

Semiconducting Transparent Thin Films

TL;DR: In this paper, a comprehensive account of the properties, growth and applications of semiconducting transparent thin films is provided, which is a valuable reference tool for the established researcher, and provides a comprehensive introcution to the subject for graduates of electrical and electronic engineering.
Journal ArticleDOI

A transparent metal: Nb-doped anatase TiO2

TL;DR: In this article, anatase Ti1−xNbxO2 films with x = 0.002-0.2 have been shown to have high resistivity and transport and optical properties comparable to those of typical TCOs, such as In2−xSnxO3 and ZnO.
Journal ArticleDOI

High mobility n‐type charge carriers in large single crystals of anatase (TiO2)

TL;DR: In this article, resistivity, thermopower, and Hall-effect measurements on large single crystals of the anatase form of TiO2 all indicate high mobility n-type carriers that are produced by thermal excitation from a density of ∼1018 cm−3 putatively present shallow donor states.
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