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Journal ArticleDOI

Fullerene-Free Polymer Solar Cells with over 11% Efficiency and Excellent Thermal Stability

TLDR
A nonfullerene-based polymer solar cell (PSC) that significantly outperforms fullerene -based PSCs with respect to the power-conversion efficiency and excellent thermal stability is demonstrated for the first time.
Abstract
A nonfullerene-based polymer solar cell (PSC) that significantly outperforms fullerene-based PSCs with respect to the power-conversion efficiency is demonstrated for the first time. An efficiency of >11%, which is among the top values in the PSC field, and excellent thermal stability is obtained using PBDB-T and ITIC as donor and acceptor, respectively.

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Citations
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Journal ArticleDOI

Molecular Optimization Enables over 13% Efficiency in Organic Solar Cells

TL;DR: The PBDB-T-SF:IT-4F-based OSC device showed a record high efficiency, and an efficiency of over 12% can be obtained with a thickness of 100-200 nm, suggesting the promise of fullerene-free OSCs in practical applications.
Journal ArticleDOI

Organic solar cells based on non-fullerene acceptors.

TL;DR: Non-fullerene OSCs show great tunability in absorption spectra and electron energy levels, providing a wide range of new opportunities, and this Review highlights these opportunities made possible by NF acceptors.
Journal ArticleDOI

Non-fullerene acceptors for organic solar cells

TL;DR: Non-fullerene acceptors (NFAs) are currently a major focus of research in the development of bulk-heterojunction organic solar cells (OSCs) as mentioned in this paper.
Journal ArticleDOI

Energy-Level Modulation of Small-Molecule Electron Acceptors to Achieve over 12% Efficiency in Polymer Solar Cells

TL;DR: The two new SMAs (IT-M and IT-DM) end-capped by methyl-modified dicycanovinylindan-1-one exhibit upshifted lowest unoccupied molecular orbital (LUMO) levels, and hence higher open-circuit voltages can be observed in the corresponding devices.
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Nonfullerene Acceptor Molecules for Bulk Heterojunction Organic Solar Cells

TL;DR: Progress is summarized, aiming to describe the molecular design strategy, to provide insight into the structure-property relationship, and to highlight the challenges the field is facing, with emphasis placed on most recent nonfullerene acceptors that demonstrated top-of-the-line photovoltaic performances.
References
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Journal ArticleDOI

Polymer photovoltaic cells : enhanced efficiencies via a network of internal donor-acceptor heterojunctions

TL;DR: In this paper, the carrier collection efficiency and energy conversion efficiency of polymer photovoltaic cells were improved by blending of the semiconducting polymer with C60 or its functionalized derivatives.
Journal ArticleDOI

Design Rules for Donors in Bulk‐Heterojunction Solar Cells—Towards 10 % Energy‐Conversion Efficiency

TL;DR: In this article, the authors presented a review of several organic photovoltaics (OPV) technologies, including conjugated polymers with high-electron-affinity molecules like C60 (as in the bulk-heterojunction solar cell).
Journal ArticleDOI

Photoinduced electron transfer from a conducting polymer to buckminsterfullerene.

TL;DR: Because the photoluminescence in the conducting polymer is quenched by interaction with C60, the data imply that charge transfer from the excited state occurs on a picosecond time scale.
Journal ArticleDOI

Polymer–Fullerene Composite Solar Cells

TL;DR: Polymer-based organic photovoltaic systems hold the promise for a cost-effective, lightweight solar energy conversion platform, which could benefit from simple solution processing of the active layer.
Journal ArticleDOI

Polymer solar cells

TL;DR: In this article, a review summarizes recent progress in the development of polymer solar cells and provides a synopsis of major achievements in the field over the past few years, while potential future developments and the applications of this technology are also briefly discussed.
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