scispace - formally typeset
Open AccessJournal ArticleDOI

Hierarchically ordered oxides

Reads0
Chats0
TLDR
Porous silica, niobia, and titania with three-dimensional structures patterned over multiple length scales were prepared by combining micromolding, polystyrene sphere templating, and cooperative assembly of inorganic sol-gel species with amphiphilic triblock copolymers.
Abstract
Porous silica, niobia, and titania with three-dimensional structures patterned over multiple length scales were prepared by combining micromolding, polystyrene sphere templating, and cooperative assembly of inorganic sol-gel species with amphiphilic triblock copolymers. The resulting materials show hierarchical ordering over several discrete and tunable length scales ranging from 10 nanometers to several micrometers. The respective ordered structures can be independently modified by choosing different mold patterns, latex spheres, and block copolymers. The examples presented demonstrate the compositional and structural diversities that are possible with this simple approach.

read more

Citations
More filters
Journal ArticleDOI

Facile preparation of mesoporous titanium nitride microspheres for electrochemical energy storage.

TL;DR: The electrochemical performance of the resultant mesoporous TiN spheres demonstrates that this material can be a promising electrode material for nonaqueous supercapacitors with high energy densities.
Journal ArticleDOI

Molecular Engineering of Functional Inorganic and Hybrid Materials

TL;DR: A short review of recent advances in this field can be found in this paper with a few selected examples related to three main research areas: the synthesis of single nano-objects and the processing of porous and hierarchically structured materials and hybrid nanocomposite materials.
Book

Handbook of Gas Sensor Materials: Properties, Advantages and Shortcomings for Applications Volume 2: New Trends and Technologies

TL;DR: The Handbook of Gas Sensor Materials : Properties, Advantages and Shortcomings for Applications Volume 2: New Trends and Technologies as mentioned in this paper is available on our book collections and it comes PDF and EPUB document format.
Journal ArticleDOI

Nanochannels for supramolecular organization of luminescent guests

TL;DR: In this paper, the mesoporous host-guest material is used for the supramolecular organization of a large variety of guest molecules, such as luminescent molecules, complexes, or nanoclusters.
Journal ArticleDOI

Topographical patterning of chemically sensitive biological materials using a polymer-based dry lift off

TL;DR: A dry lift-off method that allows patterning of chemically sensitive biological materials on a variety of surfaces using a combination of projection lithography and reactive ion etching and a Parylene coated surface is patterned and subsequently coated with a biochemical layer.
References
More filters
Journal ArticleDOI

Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism

TL;DR: In this paper, the synthesis of mesoporous inorganic solids from calcination of aluminosilicate gels in the presence of surfactants is described, in which the silicate material forms inorganic walls between ordered surfactant micelles.
Journal ArticleDOI

Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 angstrom pores

TL;DR: Use of amphiphilic triblock copolymers to direct the organization of polymerizing silica species has resulted in the preparation of well-ordered hexagonal mesoporous silica structures (SBA-15) with uniform pore sizes up to approximately 300 angstroms.
Journal ArticleDOI

Generalized syntheses of large-pore mesoporous metal oxides with semicrystalline frameworks

TL;DR: In this article, a simple and versatile procedure for the synthesis of thermally stable, ordered, large-pore (up to 140 A) mesoporous metal oxides was described.
Journal ArticleDOI

Synthesis of Macroporous Minerals with Highly Ordered Three-Dimensional Arrays of Spheroidal Voids

TL;DR: The examples presented demonstrate the compositional diversity possible with this technique and could have applications in areas ranging from quantum electronics to photocatalysis to battery materials.
Related Papers (5)