Journal ArticleDOI
Hydrogen generation from formic acid and alcohols using homogeneous catalysts
TLDR
This tutorial review describes recent progress in the development of homogeneous catalytic methodology for the direct generation of hydrogen gas from formic acid and alcohols.Abstract:
This tutorial review describes recent progress in the development of homogeneous catalytic methodology for the direct generation of hydrogen gas from formic acid and alcohols.read more
Citations
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Journal ArticleDOI
Recent advances in catalytic hydrogenation of carbon dioxide
TL;DR: A critical review of recent developments in hydrogenation reaction, with emphases on catalytic reactivity, reactor innovation, and reaction mechanism, provides an overview regarding the challenges and opportunities for future research in the field.
Journal ArticleDOI
Catalysis for the valorization of exhaust carbon: from CO2 to chemicals, materials, and fuels. technological use of CO2.
Journal ArticleDOI
Catalysis of the electrochemical reduction of carbon dioxide
TL;DR: The general trends that transpire presently and are likely to be the object of active future work emphasis is put on the favorable role of acid addition in homogeneous catalytic systems and on the crucial chemical role of the electrode material in heterogeneous catalysis.
Journal ArticleDOI
CO2 Hydrogenation to Formate and Methanol as an Alternative to Photo- and Electrochemical CO2 Reduction
TL;DR: The chiral stationary phase for high-performance liquid chromatography showed good chiral recognition ability and high efficiency in both the liquid phase and the solid-state phase.
Journal ArticleDOI
Formic acid as a hydrogen source – recent developments and future trends
Martin Grasemann,Gábor Laurenczy +1 more
TL;DR: In this article, the state of research for heterogeneous and homogeneous formic acid dehydrogenation catalysts is reviewed in detail and an outlook on necessary development steps is presented.
References
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Journal ArticleDOI
Direct Synthesis of Amides from Alcohols and Amines with Liberation of H2
TL;DR: A reaction in which primary amines are directly acylated by equimolar amounts of alcohols to produce amides and molecular hydrogen in high yields and high turnover numbers is reported.
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Hydrogen production reactions from carbon feedstocks: fossil fuels and biomass.
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Ruthenium(II)-Catalyzed Asymmetric Transfer Hydrogenation of Ketones Using a Formic Acid−Triethylamine Mixture
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Homogeneous Hydrogenation of Carbon Dioxide
TL;DR: In this article, the simplest and most studied reactions of CO{sub 2} are the catalytic reactions with H{sub 1} in the presence or absence of other reactive species.
Journal ArticleDOI
Facile Conversion of Alcohols into Esters and Dihydrogen Catalyzed by New Ruthenium Complexes
TL;DR: In this paper, an efficient, environmentally benign method for the preparation of esters from alcohols under mild, neutral conditions without the need for carboxylic acid derivatives and condensing agents was developed.
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Formic acid as a hydrogen source – recent developments and future trends
Martin Grasemann,Gábor Laurenczy +1 more