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Influence of the Support and the Size of Gold Clusters on Catalytic Activity for Glucose Oxidation
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This article is published in Angewandte Chemie.The article was published on 2008-11-17. It has received 270 citations till now. The article focuses on the topics: Heterogeneous catalysis & Catalysis.read more
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Mechanochemistry: opportunities for new and cleaner synthesis
Stuart L. James,Christopher J. Adams,Carsten Bolm,Dario Braga,Paul Collier,Tomislav Friščić,Fabrizia Grepioni,Kenneth D. M. Harris,Geoff Hyett,William Jones,Anke Krebs,James Mack,Lucia Maini,A. Guy Orpen,Ivan P. Parkin,William C. Shearouse,Jonathan W. Steed,Daniel C. Waddell +17 more
TL;DR: Concentrating on recent advances, this article covers industrial aspects, inorganic materials, organic synthesis, cocrystallisation, pharmaceutical aspects, metal complexes, supramolecular aspects and characterization methods.
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Conversion of Biomass into Chemicals over Metal Catalysts
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Particle Size Effects in the Catalytic Electroreduction of CO2 on Cu Nanoparticles
TL;DR: The presented activity-selectivity-size relations provide novel insights in the CO2 electroreduction reaction on nanoscale surfaces and lend themselves well to density functional theory (DFT) evaluation and reaction mechanism verification.
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Synergistic Catalysis of Metal–Organic Framework-Immobilized Au–Pd Nanoparticles in Dehydrogenation of Formic Acid for Chemical Hydrogen Storage
TL;DR: The resulting composites represent the first highly active MOF-immobilized metal catalysts for the complete conversion of formic acid to high-quality hydrogen at a convenient temperature for chemical hydrogen storage.
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Selective oxidation of alcohols and aldehydes over supported metal nanoparticles
TL;DR: In this article, the authors examined the literature on supported metal catalysts for the oxidation of molecules of interest in biomass conversion (primary alcohols, polyols, 5-hydroxymethylfurfural, and various sugars).
References
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Liquid-phase catalytic processing of biomass-derived oxygenated hydrocarbons to fuels and chemicals.
TL;DR: An overview of chemical catalytic transformations of biomass-derived oxygenated feedstocks in the liquid phase to value-added chemicals and fuels is presented, with specific examples emphasizing the development of catalytic processes based on an understanding of the fundamental reaction chemistry.
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When Gold Is Not Noble: Catalysis by Nanoparticles
TL;DR: The role of the perimeter interfaces of Au particles as the sites for reactions is discussed as well as the change in chemical reactivity of Au clusters composed of fewer than 300 atoms.
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The Catalytic Activity of “Naked” Gold Particles
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Alternative Methods for the Preparation of Gold Nanoparticles Supported on TiO2
TL;DR: In this article, the authors investigated other methods of preparation of Au/TiO2 catalysts to obtain small gold metal particles (2−3 nm) and a higher Au loading.
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Selective Oxidation of D-Glucose on Gold Catalyst
TL;DR: In this article, the selective oxidation of D-glucose to D-gluconic acid was performed at both controlled (7-9.5) and free pH values in an aqueous solution in the presence of a gold on carbon catalyst using dioxygen as the oxidant under mild conditions.