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Open AccessJournal ArticleDOI

Investigation on Electroreduction of CO2 to Formic Acid Using Cu3(BTC)2 Metal–Organic Framework (Cu-MOF) and Graphene Oxide

TLDR
Cu-based MOFs along with graphene oxide are synthesized and used further for reducing CO2 electrochemically and the results showed that HCOOH was the main product formed through reduction, which is carried out using a cost-effective catalyst for the conversion of CO2 to formic acid than using the commercial electrodes.
Abstract
A recent class of porous materials, viz., metal–organic frameworks (MOFs), finds applications in several areas. In this work, Cu-based MOFs (Cu–benzene-1,3,5-tricarboxylic acid) along with graphene...

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Citations
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Journal ArticleDOI

Highly Robust 3s-3d {CaZn}-Organic Framework for Excellent Catalytic Performance on Chemical Fixation of CO2 and Knoevenagel Condensation Reaction.

TL;DR: The achievements broaden the way for assembling nanoporous multifunctional MOFs by employing ligand-directed synthetic strategy, which can accelerate the transformation from simple structural research to socially demanding applications.

Cu-Based Bimetallic Electrocatalysts for CO2 Reduction

TL;DR: In this article, the authors summarize the recent progress relating to the Cu-based bimetallic electrocatalysts for CO2 reduction, and discuss the composition and structure effects on the activity and selectivity of electrochemical CO 2 reduction.
Journal ArticleDOI

Cu-based bimetallic electrocatalysts for CO2 reduction

TL;DR: In this paper , the authors summarized the recent progress relating to the Cu-based bimetallic electrocatalysts for CO2 reduction, and discussed the composition and structure effects on the activity and selectivity of electrochemical CO 2 reduction.
Journal ArticleDOI

Graphene-Based Metal–Organic Framework Hybrids for Applications in Catalysis, Environmental, and Energy Technologies

TL;DR: In this paper , a review of current knowledge concerning the growth, structure, and properties of graphene derivatives, metal-organic frameworks (MOFs), and their graphene@MOF composites as well as the associated structure-property-performance relationships is presented.
References
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Journal ArticleDOI

A chemically functionalizable nanoporous material (Cu3(TMA)2(H2O)3)n

TL;DR: In this paper, a highly porous metal coordination polymer [Cu3(TMA)2(H2O)3]n (where TMA is benzene-1,3,5-tricarboxylate) was formed in 80 percent yield.
Journal ArticleDOI

Advances in CO2 capture technology—The U.S. Department of Energy's Carbon Sequestration Program ☆

TL;DR: The current status of the development of CO2 capture technology is discussed in this article, where a wide variety of separation techniques are being pursued, including gas phase separation, absorption into a liquid, and adsorption on a solid, as well as hybrid processes, such as adhesions/membrane systems.
Journal ArticleDOI

Electrocatalytic and homogeneous approaches to conversion of CO2 to liquid fuels

TL;DR: This tutorial review will present much of the significant work that has been done in the field of electrocatalytic and homogeneous reduction of carbon dioxide over the past three decades and extend the discussion to the important conclusions from previous work and recommendations for future directions to develop a catalytic system that will convert carbon dioxide to liquid fuels with high efficiencies.
Book ChapterDOI

Electrochemical CO2 Reduction on Metal Electrodes

TL;DR: In this article, the authors defined the energy conversion efficiency, defined as the ratio of the free energy of the products obtained in electrochemical CO2 reduction and that consumed in the reduction, would be roughly 30 to 40%.
Journal ArticleDOI

Aqueous CO2 reduction at very low overpotential on oxide-derived Au nanoparticles.

TL;DR: Electrokinetic studies indicate that the improved catalysis is linked to dramatically increased stabilization of the CO(2)(•-) intermediate on the surfaces of the oxide-derived Au electrodes.
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