Journal ArticleDOI
Electrocatalytic and homogeneous approaches to conversion of CO2 to liquid fuels
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TLDR
This tutorial review will present much of the significant work that has been done in the field of electrocatalytic and homogeneous reduction of carbon dioxide over the past three decades and extend the discussion to the important conclusions from previous work and recommendations for future directions to develop a catalytic system that will convert carbon dioxide to liquid fuels with high efficiencies.Abstract:
Research in the field of catalytic reduction of carbon dioxide to liquid fuels has grown rapidly in the past few decades. This is due to the increasing amount of carbon dioxide in the atmosphere and a steady climb in global fuel demand. This tutorial review will present much of the significant work that has been done in the field of electrocatalytic and homogeneous reduction of carbon dioxide over the past three decades. It will then extend the discussion to the important conclusions from previous work and recommendations for future directions to develop a catalytic system that will convert carbon dioxide to liquid fuels with high efficiencies.read more
Citations
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Electrocatalysis for the oxygen evolution reaction: recent development and future perspectives
TL;DR: This review acquaints some materials for performing OER activity, in which the metal oxide materials build the basis of OER mechanism while non-oxide materials exhibit greatly promising performance toward overall water-splitting.
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Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions
TL;DR: The emphasis of this review is on the origin of the electrocatalytic activity of nanostructured catalysts toward a series of key clean energy conversion reactions by correlating the apparent electrode performance with their intrinsic electrochemical properties.
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Solar Energy Supply and Storage for the Legacy and Nonlegacy Worlds
Timothy R. Cook,Dilek K. Dogutan,Steven Y. Reece,Yogesh Surendranath,Thomas S. Teets,Daniel G. Nocera +5 more
TL;DR: The Scope of Review: Large-Scale Centralized Energy Storage, Chemical Energy Storage: Solar Fuels, and Capacitors 6486 5.1.2.
Journal ArticleDOI
Recent advances in catalytic hydrogenation of carbon dioxide
TL;DR: A critical review of recent developments in hydrogenation reaction, with emphases on catalytic reactivity, reactor innovation, and reaction mechanism, provides an overview regarding the challenges and opportunities for future research in the field.
Journal ArticleDOI
Photocatalytic reduction of CO2 on TiO2 and other semiconductors.
Severin N. Habisreutinger,Severin N. Habisreutinger,Severin N. Habisreutinger,Lukas Schmidt-Mende,Lukas Schmidt-Mende,Jacek K. Stolarczyk +5 more
TL;DR: In this paper, the authors present a review of the current approaches for the heterogeneous photocatalytic reduction of CO2 on TiO2 and other metal oxide, oxynitride, sulfide, and phosphide semiconductors.
References
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Journal ArticleDOI
Molecular Catalysis of Electrochemical Reactions. Mechanistic Aspects
TL;DR: Ruthenium Complexes as a Source of Inspiration, Reduction of Carbon Dioxide, and Concluding Remarks.
Journal ArticleDOI
Electrocatalytic reduction of carbon dioxide by using macrocycles of nickel and cobalt
TL;DR: In this article, an indirect method for the reduction of CO/sub 2/ in nonaqueous solutions and involving initial reduction of metal complexes and their subsequent reduction with CO/ sub 2/ is described.
Journal ArticleDOI
Electrocatalytic reduction of carbon dioxide mediated by Re(bipy)(CO)3Cl (bipy = 2,2′-bipyridine)
TL;DR: The Re(bipy)(CO)3Cl (Bipy = 2,2′-bipyridine) is an efficient homogeneous catalyst for the selective and sustained electrochemical reduction of CO2 to CO at low potential.
Journal ArticleDOI
Electrocatalytic reduction of carbon dioxide by nickel cyclam2+ in water: study of the factors affecting the efficiency and the selectivity of the process.
TL;DR: The mechanistic investigation presently described points to the importance of molecular species adsorbed on the cathode surface and the size of the cyclam ligand and the presence of secondary amine groups (NH) might account for the very special properties of the electrocatalyst.
Journal ArticleDOI
Carbon dioxide activation at the Ni,Fe-cluster of anaerobic carbon monoxide dehydrogenase.
Jae-Hun Jeoung,Holger Dobbek +1 more
TL;DR: The structures define the mechanism of CO oxidation and CO2 reduction at the Ni-Fe site of cluster C, where CO2 acts as a bridging ligand between Ni and the asymmetrically coordinated Fe, where it completes the square-planar coordination of the Ni ion.
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