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Manganese oxides for lithium batteries

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This article is published in Progress in Solid State Chemistry.The article was published on 1997-01-01. It has received 1332 citations till now. The article focuses on the topics: Lithium vanadium phosphate battery & Lithium.

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λ-MnO2 nanodisks and their magnetic properties

TL;DR: In this article, highly crystalline λ-MnO2 nanodisks are synthesized via a simple microemulsion process by using polyvinylpyrrolidone (PVP) as a capping layer.
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Strategies for improving electrochemical reaction kinetics of cathode materials for subzero-temperature Li-ion batteries: A review

TL;DR: In this paper , a review of the recent important advances in improving the electrochemical reaction kinetics for the subzero operations of Li-ion batteries based on the cathode perspective is summarized.
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Preparation and characterization of o-LiMnO2 cathode materials

TL;DR: In this article, small particle-sized orthorhombic LiMnO 2 powders were prepared via Pechini's route with Li/Mn molar ratio ranging between 1.00 and 1.20, followed by calcinations at 300-°C in air and heat-treatment at temperatures between 700 and 900°C for various durations under flowing nitrogen.
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Stabilization of Spinel-like Phase Transformation of o-LiMnO2 during 55 °C Cycling by Sol−Gel Coating of CoO

TL;DR: In this paper, a low-temperature sol−gel coating of CoO on orthorhombic LiMnO2 particles greatly stabilizes spinel-like phase transformation during electrochemical cycling at 55 °C.
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Ultrasound-assisted synthesis of Li-rich mesoporous LiMn2O4 nanospheres for enhancing the electrochemical performance in Li-ion secondary batteries

TL;DR: It is demonstrated that mesoporous U-LMO nanospheres were fabricated to enhance the electrochemical performance and protect it from structurally significant collapsing because of high crystallinity.
References
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LixCoO2 (0<x<-1): A new cathode material for batteries of high energy density

TL;DR: In this paper, a new system LixCoO2 (0 Li x CoO 2 Li ) is proposed, which shows low overvoltages and good reversibility for current densities up to 4 mA cm−2 over a large range of x.
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Zero‐Strain Insertion Material of Li [ Li1 / 3Ti5 / 3 ] O 4 for Rechargeable Lithium Cells

TL;DR: In this paper, a defect spinel-framework structure was examined in nonaqueous lithium cells and it was shown that the lattice dimension did not change during the reaction since the reaction consists of lithium ion and electron insertion into/extraction from the solid matrix without a noticeable change in lattice dimensions.
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Lithium insertion into manganese spinels

TL;DR: In this article, Li has been inserted chemically and electrochemically into Mn3O4 and Li[Mn2]O4 at room temperature from X-ray diffraction.
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Electrochemical and In Situ X‐Ray Diffraction Studies of Lithium Intercalation in Li x CoO2

TL;DR: In this article, high precision voltage measurements and in situ x-ray diffraction indicate a sequence of three distinct phase transitions as varies from 1 to 0.4, two of which are situated slightly above and below and are caused by an order/disorder transition of the lithium ions.
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Improved capacity retention in rechargeable 4 V lithium/lithium- manganese oxide (spinel) cells

TL;DR: In this article, the authors improved the rechargeable capacity of 4 V LixMn2O4 spinel cathodes by modifying the composition of the spinel electrode, achieving a capacity in excess of 100 mAh/g in flooded-electrolyte lithium cells.
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