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Manganese oxides for lithium batteries

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This article is published in Progress in Solid State Chemistry.The article was published on 1997-01-01. It has received 1332 citations till now. The article focuses on the topics: Lithium vanadium phosphate battery & Lithium.

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Electrolytic Manganese Dioxide Coatings on High Aspect Ratio Micro-Pillar Arrays for 3D Thin Film Lithium Ion Batteries.

TL;DR: A conformal electrolytic MnO2 (EMD) coating is successfully achieved on high aspect ratio C/TiN/Si pillar arrays by tailoring the deposition process.
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Development of lithium-ion batteries from micro-structured to nanostructured materials: its issues and challenges.

TL;DR: This work is primarily focused on development of Li-ion batteries from micro-structured to nanostructured materials and some of the critical issues namely, electrode preparation, synthesis, and electrochemical characterization.
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NMR Determination of the Relative Binding Affinity of Crown Ethers for Manganese Cations in Aprotic Nonaqueous Lithium Electrolyte Solutions

TL;DR: In this article, the relative binding affinity of crown ethers for manganese cations in a lithium-containing environment through the detection of the 7Li nucleus chemical shift was evaluated.
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Effect of Dopants on the Functional Properties of Lithium-Rich Cathode Materials for Lithium-Ion Batteries

TL;DR: In this paper, the effect of the dopant nature on the electrochemical performance of lithium-rich oxides of the general composition 0.5LiMn0.33Ni0.31M0.02O2 (M = Mg, Cr, Zr).

Computational study of the transport mechanisms of molecules and ions in solid materials

TL;DR: Zhang et al. as discussed by the authors used ab initio calculations and molecular dynamics simulations to investigate the mechamisn of ions and molecules in solids, and showed that progress in the understanding of the ionic and molecular transport mechanisms can be used to substantially increase the performance of devices.
References
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LixCoO2 (0<x<-1): A new cathode material for batteries of high energy density

TL;DR: In this paper, a new system LixCoO2 (0 Li x CoO 2 Li ) is proposed, which shows low overvoltages and good reversibility for current densities up to 4 mA cm−2 over a large range of x.
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Zero‐Strain Insertion Material of Li [ Li1 / 3Ti5 / 3 ] O 4 for Rechargeable Lithium Cells

TL;DR: In this paper, a defect spinel-framework structure was examined in nonaqueous lithium cells and it was shown that the lattice dimension did not change during the reaction since the reaction consists of lithium ion and electron insertion into/extraction from the solid matrix without a noticeable change in lattice dimensions.
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Lithium insertion into manganese spinels

TL;DR: In this article, Li has been inserted chemically and electrochemically into Mn3O4 and Li[Mn2]O4 at room temperature from X-ray diffraction.
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Electrochemical and In Situ X‐Ray Diffraction Studies of Lithium Intercalation in Li x CoO2

TL;DR: In this article, high precision voltage measurements and in situ x-ray diffraction indicate a sequence of three distinct phase transitions as varies from 1 to 0.4, two of which are situated slightly above and below and are caused by an order/disorder transition of the lithium ions.
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Improved capacity retention in rechargeable 4 V lithium/lithium- manganese oxide (spinel) cells

TL;DR: In this article, the authors improved the rechargeable capacity of 4 V LixMn2O4 spinel cathodes by modifying the composition of the spinel electrode, achieving a capacity in excess of 100 mAh/g in flooded-electrolyte lithium cells.
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