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Manganese oxides for lithium batteries

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This article is published in Progress in Solid State Chemistry.The article was published on 1997-01-01. It has received 1332 citations till now. The article focuses on the topics: Lithium vanadium phosphate battery & Lithium.

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Electrochemical characterization of high-surface-area catalysts and other nanoscale electroactive materials at sticky-carbon electrodes

TL;DR: In this article, a hand-pressing of solids onto the surface of a carbon-wax composite electrode has been used for direct quantitative analysis of submilligram quantities of nanoscale, high-surface-area electroactive powders.
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LiMn2O4 nanorods synthesized by MnOOH template for lithium-ion batteries with good performance

TL;DR: LiMn 2 O 4 nanorods have been synthesized through a solid state reaction at 700°C for 10h by using MnOOH nanorod as the template which were obtained by a hydrothermal route.
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Evolution of Nanostructured Manganese (Oxyhydr)oxides in Water through MnO4− Reduction

TL;DR: In this article, the reactivity of S2O32− as a reducing agent is tuned by the temperature in order to selectively synthesize manganite γ-MnOOH at 60 °C and hausmannite Mn3O4 at 95 °C.
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Facile synthesis route to highly crystalline mesoporous γ-MnO2 nanospheres

TL;DR: In this article, hierarchical mesoporous γ-MnO2 nanospheres with high crystallinity were prepared by a template-free self-assembly under applied ultrasonic waves, resulting in a solid spherical nanostructure with stacking of nanosized worm-like particles.
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Electronic Structure of CdS Cores in Cd Thiolate Complexes and Clusters

TL;DR: In this paper, the electronic structure of small clusters forming the inorganic cores in cadmium thiolate complexes is analyzed on the basis of semi-empirical quantum chemical calculations.
References
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LixCoO2 (0<x<-1): A new cathode material for batteries of high energy density

TL;DR: In this paper, a new system LixCoO2 (0 Li x CoO 2 Li ) is proposed, which shows low overvoltages and good reversibility for current densities up to 4 mA cm−2 over a large range of x.
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Zero‐Strain Insertion Material of Li [ Li1 / 3Ti5 / 3 ] O 4 for Rechargeable Lithium Cells

TL;DR: In this paper, a defect spinel-framework structure was examined in nonaqueous lithium cells and it was shown that the lattice dimension did not change during the reaction since the reaction consists of lithium ion and electron insertion into/extraction from the solid matrix without a noticeable change in lattice dimensions.
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Lithium insertion into manganese spinels

TL;DR: In this article, Li has been inserted chemically and electrochemically into Mn3O4 and Li[Mn2]O4 at room temperature from X-ray diffraction.
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Electrochemical and In Situ X‐Ray Diffraction Studies of Lithium Intercalation in Li x CoO2

TL;DR: In this article, high precision voltage measurements and in situ x-ray diffraction indicate a sequence of three distinct phase transitions as varies from 1 to 0.4, two of which are situated slightly above and below and are caused by an order/disorder transition of the lithium ions.
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Improved capacity retention in rechargeable 4 V lithium/lithium- manganese oxide (spinel) cells

TL;DR: In this article, the authors improved the rechargeable capacity of 4 V LixMn2O4 spinel cathodes by modifying the composition of the spinel electrode, achieving a capacity in excess of 100 mAh/g in flooded-electrolyte lithium cells.
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