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Manganese oxides for lithium batteries

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This article is published in Progress in Solid State Chemistry.The article was published on 1997-01-01. It has received 1332 citations till now. The article focuses on the topics: Lithium vanadium phosphate battery & Lithium.

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Book ChapterDOI

Nanowires and Nanotubes of Complex Oxides

TL;DR: In this article, the authors investigated the photochemical and photophysical properties of carbon nanotubes (C-NTs) and found enhanced photochemical properties different from that of bulky or nanoparticle materials.
Journal ArticleDOI

The effects of vanadium substitution on one-dimensional tunnel structures of cryptomelane: Combined TEM and DFT study

TL;DR: In this paper, the substitution of manganese (Mn) atoms in the tunnel wall with vanadium (V)-substituted one-dimensional cryptomelane as a model material to study structural features critical to electrochemical reversibility of the cathode in lithium-ion batteries.
Journal ArticleDOI

The impact of K+ content on the structural transformations and morphological changes during the thermal treatment of α-MnO2 nanorods

TL;DR: In this article, the effect of heat treatment on the structure and morphology of α-MnO 2 nanorods with different potassium contents was investigated, and the first structural and morphological changes were observed when the nanorod was heated at 800 and 1100°C, respectively.
Journal ArticleDOI

Mn 2p resonant X-ray emission clarifies the redox reaction and charge-transfer effects in LiMn2O4

TL;DR: High-energy-resolution soft X-ray emission spectroscopy was applied to understand the changes in the electronic structure of LiMn2O4 upon Li-ion extraction/insertion, which suggests very strong hybridization between the Mn 3d and O 2p orbitals.
Journal ArticleDOI

Influence of Co-substitution on Structure and Electrochemical Performances of Li-rich Spinel LiMn2O4

TL;DR: In this article, a spinel LiMn2O4 was synthesized by solid-state reaction using Mn2O3 as Mn source, and the influence of Co-substitution on structure and electrochemical performances of spinel Lm2O 4 was researched.
References
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Journal ArticleDOI

LixCoO2 (0<x<-1): A new cathode material for batteries of high energy density

TL;DR: In this paper, a new system LixCoO2 (0 Li x CoO 2 Li ) is proposed, which shows low overvoltages and good reversibility for current densities up to 4 mA cm−2 over a large range of x.
Journal ArticleDOI

Zero‐Strain Insertion Material of Li [ Li1 / 3Ti5 / 3 ] O 4 for Rechargeable Lithium Cells

TL;DR: In this paper, a defect spinel-framework structure was examined in nonaqueous lithium cells and it was shown that the lattice dimension did not change during the reaction since the reaction consists of lithium ion and electron insertion into/extraction from the solid matrix without a noticeable change in lattice dimensions.
Journal ArticleDOI

Lithium insertion into manganese spinels

TL;DR: In this article, Li has been inserted chemically and electrochemically into Mn3O4 and Li[Mn2]O4 at room temperature from X-ray diffraction.
Journal ArticleDOI

Electrochemical and In Situ X‐Ray Diffraction Studies of Lithium Intercalation in Li x CoO2

TL;DR: In this article, high precision voltage measurements and in situ x-ray diffraction indicate a sequence of three distinct phase transitions as varies from 1 to 0.4, two of which are situated slightly above and below and are caused by an order/disorder transition of the lithium ions.
Journal ArticleDOI

Improved capacity retention in rechargeable 4 V lithium/lithium- manganese oxide (spinel) cells

TL;DR: In this article, the authors improved the rechargeable capacity of 4 V LixMn2O4 spinel cathodes by modifying the composition of the spinel electrode, achieving a capacity in excess of 100 mAh/g in flooded-electrolyte lithium cells.
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