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Manganese oxides for lithium batteries

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This article is published in Progress in Solid State Chemistry.The article was published on 1997-01-01. It has received 1332 citations till now. The article focuses on the topics: Lithium vanadium phosphate battery & Lithium.

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Anomalous effect of K ion on crystallinity and capacitance of the manganese dioxide

TL;DR: In this paper, the effect of the content of K ion on crystalline state and capacitance behavior of MnO 2 was investigated, and it was found that with the increasing content of k ion, manganese dioxide is more likely to maintain amorphous, while adding Li +, Na +, or NH 4 + has no such effect.
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Search for new manganese–cobalt oxides as positive electrode materials for lithium batteries

TL;DR: In this paper, two new mixed manganese-cobalt oxides for lithium battery positive electrode materials were obtained using original synthesis routes, and the effect of cobalt content on its electrochemical behaviour was reported in detail here.
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Direct Monolithic Integration of Vertical Single Crystalline Octahedral Molecular Sieve Nanowires on Silicon

TL;DR: In this paper, the authors developed an original strategy to produce vertical epitaxial single crystalline manganese oxide octahedral molecular sieve (OMS) nanowires with tunable pore sizes and compositions on silicon substrates by using a chemical solution deposition approach.
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Electronic structure and magnetic properties of LiMn1.5M0.5O4 (M=Al, Mg, Ni, Fe) and LiMn2O4/TiO2 nanocrystalline electrode materials

TL;DR: In this article, the process of sol-gel synthesis was applied to obtain LiMn 1.5 M 0.5 O 4 (M =Al, Mg, Ni, Fe) and Li Mn 2 O 4 /TiO 2 nanopowders.
References
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LixCoO2 (0<x<-1): A new cathode material for batteries of high energy density

TL;DR: In this paper, a new system LixCoO2 (0 Li x CoO 2 Li ) is proposed, which shows low overvoltages and good reversibility for current densities up to 4 mA cm−2 over a large range of x.
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Zero‐Strain Insertion Material of Li [ Li1 / 3Ti5 / 3 ] O 4 for Rechargeable Lithium Cells

TL;DR: In this paper, a defect spinel-framework structure was examined in nonaqueous lithium cells and it was shown that the lattice dimension did not change during the reaction since the reaction consists of lithium ion and electron insertion into/extraction from the solid matrix without a noticeable change in lattice dimensions.
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Lithium insertion into manganese spinels

TL;DR: In this article, Li has been inserted chemically and electrochemically into Mn3O4 and Li[Mn2]O4 at room temperature from X-ray diffraction.
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Electrochemical and In Situ X‐Ray Diffraction Studies of Lithium Intercalation in Li x CoO2

TL;DR: In this article, high precision voltage measurements and in situ x-ray diffraction indicate a sequence of three distinct phase transitions as varies from 1 to 0.4, two of which are situated slightly above and below and are caused by an order/disorder transition of the lithium ions.
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Improved capacity retention in rechargeable 4 V lithium/lithium- manganese oxide (spinel) cells

TL;DR: In this article, the authors improved the rechargeable capacity of 4 V LixMn2O4 spinel cathodes by modifying the composition of the spinel electrode, achieving a capacity in excess of 100 mAh/g in flooded-electrolyte lithium cells.
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