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Manganese oxides for lithium batteries

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This article is published in Progress in Solid State Chemistry.The article was published on 1997-01-01. It has received 1332 citations till now. The article focuses on the topics: Lithium vanadium phosphate battery & Lithium.

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EQCM Investigation of the Electrodeposition of MnO2 and Its Capacitance Behavior

TL;DR: In this article, the cyclic voltammetric behavior of Au in these electrolytes was studied using electrochemical quartz-crystal microbalance (EQCM) data of mass variation during cycling, the rate of electrodeposition of MnO2 is higher in the neutral medium than in the acidic medium.
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Effect of Cr3+ doping on morphology evolution and electrochemical performance of LiNi0·5Mn1·5O4 material for Li-ion battery

TL;DR: LiNi0.5-x/2CrxMn1.4-O4 (LiNi 0.475Cr0·05Mn 1·475O4) material with Cr3+ doping was investigated in this article, where the effects of different doping contents on the structure, morphology and electrochemical performance were systematically investigated.
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Effect of Copper Doping on Intercalation Properties of Amorphous Manganese Oxides Prepared by Oxidation of Mn(II) Precursors

TL;DR: Copper-doped amorphous manganese oxides were synthesized via a room-temperature aqueous solution route involving oxidation of Mn(II) precursors as discussed by the authors.
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Enhanced room temperature magnetoresistance effect in oxygen defective β-MnO2 microcrystal

TL;DR: In this paper, a rod-like β-MnO 2 microcrystals have been synthesized via a urea mediated hydrothermal method and the magnetoresistance ratio reaches an abrupt peak and then slowly increases with temperature, exceeding 50% at room temperature under 5.0 T.
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Effects of precursor treatment on the structure and electrochemical properties of spinel LiMn2O4 cathode

TL;DR: In this article, the effects of precursor treatment on the structure, morphology, and electrochemical performance of the synthesized spinel LiMn 2 O 4 are studied using contrasting experiments involving the addition of hydrazine, N 2, and H 2 O 2.
References
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LixCoO2 (0<x<-1): A new cathode material for batteries of high energy density

TL;DR: In this paper, a new system LixCoO2 (0 Li x CoO 2 Li ) is proposed, which shows low overvoltages and good reversibility for current densities up to 4 mA cm−2 over a large range of x.
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Zero‐Strain Insertion Material of Li [ Li1 / 3Ti5 / 3 ] O 4 for Rechargeable Lithium Cells

TL;DR: In this paper, a defect spinel-framework structure was examined in nonaqueous lithium cells and it was shown that the lattice dimension did not change during the reaction since the reaction consists of lithium ion and electron insertion into/extraction from the solid matrix without a noticeable change in lattice dimensions.
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Lithium insertion into manganese spinels

TL;DR: In this article, Li has been inserted chemically and electrochemically into Mn3O4 and Li[Mn2]O4 at room temperature from X-ray diffraction.
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Electrochemical and In Situ X‐Ray Diffraction Studies of Lithium Intercalation in Li x CoO2

TL;DR: In this article, high precision voltage measurements and in situ x-ray diffraction indicate a sequence of three distinct phase transitions as varies from 1 to 0.4, two of which are situated slightly above and below and are caused by an order/disorder transition of the lithium ions.
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Improved capacity retention in rechargeable 4 V lithium/lithium- manganese oxide (spinel) cells

TL;DR: In this article, the authors improved the rechargeable capacity of 4 V LixMn2O4 spinel cathodes by modifying the composition of the spinel electrode, achieving a capacity in excess of 100 mAh/g in flooded-electrolyte lithium cells.
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