Journal ArticleDOI
Mechanochemical constructing ordered rhombic channels in graphyne analogues for rapid potassium-ion storage
Yang Chen,Qiaodan Li,Wenjie Wang,Yuxuan Lu,Chengli He,Dong Qiu,Xiaoli Cui +6 more
- Vol. 8, Iss: 4, pp 044012
TLDR
In this paper, the pyridinic-N atoms in NH-rGY can efficiently manipulate electron distribution and tailor structural arrangement, endowing unique AA-stacking mode with ordered vertical rhombic channels, board interlayer spacing of 4.1 A (1.16 times to that of HH- rGY), and negligible volumetric expansion (< 3%) during potassiation, which are investigated by experiments and theoretical calculations.Abstract:
Constructing a new topological structure with unique ordered channels for rapid potassiation kinetics is crucial to ameliorating the inherent drawbacks of carbon anodes, arising from the large K-ion radius, such as huge volume expansion, slow diffusion rate, and poor interfacial transfer dynamics. Herein, dihydrogen- and nitrogen/hydrogen-substituted rhombic graphynes (HH-rGY, NH-rGY) were synthesized through a mechanochemical cross-coupling method using specific D2h-symmetric tetrahalogenated organic molecules and alkynyl-containing calcium carbide as precursors. The pyridinic-N atoms in NH-rGY can efficiently manipulate electron distribution and tailor structural arrangement, endowing unique AA'-stacking mode with ordered vertical rhombic channels, board interlayer spacing of 4.1 A (1.16 times to that of HH-rGY), and negligible volumetric expansion (< 3%) during potassiation, which are investigated by experiments and theoretical calculations. Instead of a common capacitive-dominated storage mechanism, intercalation-dominated K-storage is verified in rhombic graphynes by quantitative kinetics analysis. Especially, the NH-rGY electrode delivers a reversible capacity of 230 mAh g-1 at 50 mA g-1 (90.2% after 500 cycles) and 97 mAh g-1 at 5 A g-1 and retains 146 mAh g-1 at 2 A g-1 after 5000 cycles, owing to outstanding structural stability and rapid in-plane and inter-layer K+ diffusion. This work proposes a universal mechanochemical cross-coupling synthetic methodology and brings new insight into the topological structure design of carbon skeletons for high-performance potassium storage.read more
Citations
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Journal ArticleDOI
Bias-free synthesis of hydrogen peroxide from photo-driven oxygen reduction reaction using N-doped γ-graphyne catalyst
Liming Dai,Xiaoli Cui +1 more
TL;DR: In this paper , a metal-free N-doped γ-graphyne catalyst and wired it with n-type semiconductor photoanodes was used to generate hydrogen peroxide (H2O2) via selective 2e-ORR powered by sunlight.
Journal ArticleDOI
Bias-free synthesis of hydrogen peroxide from photo-driven oxygen reduction reaction using N-doped γ-graphyne catalyst
Liming Dai,Li Qiaodan,Li Qiaodan,Yang Chen,Xiaoli Cui,Feng Du,Feng Du,Xiaoli Cui,Liming Dai,Liming Dai +9 more
TL;DR: In this paper, a metal-free N doped γ-graphyne catalyst and wired it with n-type semiconductor photoanodes was used to generate hydrogen peroxide (H2O2) via selective 2e-ORR powered by sunlight.
Journal ArticleDOI
Defect engineering of graphynes for energy storage and conversion
TL;DR: In this article , the research progress of defect engineering of graphynes in energy storage, electrocatalysis and photocatalysis is reviewed, and the opportunities and challenges for the future research on defective graphynes are discussed.
Journal ArticleDOI
Regulating symmetry of organic precursors for mechanochemical synthesizing rich pyridonic-/pyridinic-nitrogen doped graphyne
Xiaoli Cui,Siying Li +1 more
TL;DR: In this paper , a competitive formation mechanism between NGY and graphitic carbon species is proposed according to experimental results and theoretical calculation, and an optimized NGY (1:1 molar ratio of asymmetric pentachloropyridine (PCP) or symmetric hexabromobenzene (HBB) was obtained.
References
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Journal ArticleDOI
Architecture of graphdiyne nanoscale films
TL;DR: A methodology to generate large area graphdiyne films with 3.61 cm(2) on the surface of copper via a cross-coupling reaction using hexaethynylbenzene is demonstrated and shows conductivity of 2.516 x 10(-4) S m(-1) indicating a semiconductor property.
Journal ArticleDOI
Carbon Electrodes for K-Ion Batteries
Zelang Jian,Wei Luo,Xiulei Ji +2 more
TL;DR: To improve the performance of carbon K-ion anodes, this work synthesized a nongraphitic soft carbon that exhibits cyclability and rate capability much superior to that of graphite.
Journal ArticleDOI
Graphdiyne and graphyne: from theoretical predictions to practical construction
TL;DR: A state-of-the-art research into graphdiynes and graphynes is summarized, with a focus on the latest theoretical and experimental results.
Journal ArticleDOI
Highly nitrogen doped carbon nanofibers with superior rate capability and cyclability for potassium ion batteries
TL;DR: A soft carbon anode, namely highly nitrogen-doped soft carbon nanofibers, with superior rate capability and cyclability based on a surface dominated charge storage mechanism is reported.
Journal ArticleDOI
Potassium Ion Batteries with Graphitic Materials
Wei Luo,Jiayu Wan,Burak Ozdemir,Wenzhong Bao,Yanan Chen,Jiaqi Dai,Hao Lin,Yue Xu,Feng Gu,Veronica Barone,Liangbing Hu +10 more
TL;DR: It is reported for the first time that potassium (K) ions can electrochemically intercalate into graphitic materials, such as graphite and reduced graphene oxide (RGO) at ambient temperature and pressure.