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Metal-free catalysts for oxygen reduction reaction.

TLDR
This paper presents a probabilistic procedure for estimating the polymethine content of carbon dioxide using a straightforward two-step procedure, and shows good results in both the stationary and the liquid phase.
Abstract
Liming Dai,*,†,‡ Yuhua Xue,†,‡ Liangti Qu,* Hyun-Jung Choi, and Jong-Beom Baek* †Center of Advanced Science and Engineering for Carbon (Case4Carbon), Department of Macromolecular Science and Engineering, Case Western Reserve University, 10900 Euclid Avenue, Cleveland, Ohio 44106, United States Key Laboratory of Cluster Science, Ministry of Education of China, Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, Department of Chemistry, School of Science, Beijing Institute of Technology, Beijing 100081, People’s Republic of China School of Energy and Chemical Engineering/Center for Dimension-Controllable Covalent Organic Frameworks, Ulsan National Institute of Science and Technology (UNIST), 100 Banyeon, Ulsan, 689-798, South Korea

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Citations
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Active sites of nitrogen-doped carbon materials for oxygen reduction reaction clarified using model catalysts

TL;DR: In this paper, the oxygen reduction reaction (ORR) active site was characterized by using newly designed graphite (highly oriented pyrolitic graphite) model catalysts with well-defined π conjugation and well-controlled doping of N species.
Journal ArticleDOI

Cocatalysts for Selective Photoreduction of CO2 into Solar Fuels.

TL;DR: Various cocatalysts, such as the biomimetic, metal-based,Metal-free, and multifunctional ones, and their selectivity for CO2 photoreduction are summarized and discussed, along with the recent advances in this area.
Journal ArticleDOI

Emerging Two-Dimensional Nanomaterials for Electrocatalysis

TL;DR: The fundamental relationships between electronic structure, adsorption energy, and apparent activity for a wide variety of 2D electrocatalysts are described with the goal of providing a better understanding of these emerging nanomaterials at the atomic level.
Journal ArticleDOI

Defect Chemistry of Nonprecious-Metal Electrocatalysts for Oxygen Reactions

TL;DR: The recent development of this concept is reviewed here and a novel principle for the design of oxygen electrocatalysts is proposed and an overview of the defects in carbon-based, metal-free electrocatalysis for ORR and various defects in metal oxides/selenides for OER is provided.

Structural (n,m) determination of isolated single wall carbon nanotubes by resonant Raman scattering

TL;DR: In this paper, a unique chirality assignment was made for both metallic and semiconducting nanotubes of diameter d(t), using the parameters gamma(0) = 2.9 eV and omega(RBM) = 248/d(t).
References
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Journal ArticleDOI

Nitrogen‐Doped Ordered Mesoporous Graphitic Arrays with High Electrocatalytic Activity for Oxygen Reduction

TL;DR: Nonprecious-metal and metal-free catalysts for ORR have attracted enormous interest as an alternative to platinum-based catalysts and would aid attempts to elucidate the correlation between the structure, composition, and electrochemical activity of nitrogen-doped carbon materials.
Journal ArticleDOI

Review of solutions to global warming, air pollution, and energy security

TL;DR: In this paper, the authors present a review and ranking of energy-related solutions to global warming, air pollution mortality, and energy security while considering other impacts of the proposed solutions, such as on water supply, land use, wildlife, resource availability, thermal pollution, water chemical pollution, nuclear proliferation, and undernutrition.
Journal Article

Review of solutions to global warming, air pollution and energy security

TL;DR: In this paper, the authors present a review and ranking of energy-related solutions to global warming, air pollution mortality, and energy security while considering other impacts of the proposed solutions, such as on water supply, land use, wildlife, resource availability, thermal pollution, water chemical pollution, nuclear proliferation, and undernutrition.
Journal ArticleDOI

Growth of graphene from solid carbon sources

TL;DR: It is demonstrated that large area, high-quality graphene with controllable thickness can be grown from different solid carbon sources—such as polymer films or small molecules—deposited on a metal catalyst substrate at temperatures as low as 800 °C.
Journal ArticleDOI

Structural ( n, m) determination of isolated single-wall carbon nanotubes by resonant Raman scattering.

TL;DR: It is shown that the Raman scattering technique can give complete structural information for one-dimensional systems, such as carbon nanotubes, by measuring one radial breathing mode frequency omega(RBM) and using the theory of resonant transitions.
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