Open AccessDOI
N-Sulfanylimides as the Sulfur Source for Alkyl Allenyl Sulfoxides via [2,3]-Sigmatropic Rearrangement
Adam B. Riddell,Michelle M. Michalski,Monika R. Snowdon,Mark J. Hirst,Adrian L. Schwan +4 more
- Vol. 6, Iss: 41, pp 11331-11336
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The article was published on 2021-11-08 and is currently open access. It has received 2 citations till now. The article focuses on the topics: Sigmatropic reaction & 2,3-sigmatropic rearrangement.read more
Citations
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Journal ArticleDOI
One-pot thiol-free synthetic approach to sulfides, and sulfoxides selectively
TL;DR: In this article , a facile and efficient thiol-free one-pot method for direct synthesis of sulfides and sulfoxides under green conditions without using any metal catalyst is reported.
Journal ArticleDOI
Synthesis of alkyl allenyl sulfoxides from thiosuccinimides via [2,3]-sigmatropic rearrangement
TL;DR: In this article , a variety of alkyl allenyl sulfoxides were synthesized in fair to good yields (21−73%, 21 examples) with the optimized conditions of excess propargyl alcohol and potassium carbonate in chloroform at 50°C.
References
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Hydrosulfonylation of Alkenes with Sulfonyl Chlorides under Visible Light Activation.
Sandrine M. Hell,Claudio F. Meyer,Claudio F. Meyer,Antonio Misale,Jeroen B. I. Sap,Kirsten K. Christensen,Michael C. Willis,Andrés A. Trabanco,Véronique Gouverneur +8 more
TL;DR: It is reported that tris(trimethylsilyl)silane is an ideal hydrogen atom donor enabling highly effective photoredox‐catalyzed hydrosulfonylation of electron‐deficient alkenes with sulfonyl chlorides.
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Synthesis and applications of sodium sulfinates (RSO2Na): a powerful building block for the synthesis of organosulfur compounds
TL;DR: Sodium sulfinates have been used extensively in the preparation of organosulfur compounds through S-S, N−S, and C-S bond-forming reactions as discussed by the authors.
Journal ArticleDOI
Remarkably Mild and Simple Preparation of Sulfenate Anions from β-Sulfinylesters: A New Route to Enantioenriched Sulfoxides
TL;DR: A general, efficient, and experimentally simple method for the generation of sulfenate salts has been developed using beta-sulfinylesters as substrates using a retro-Michael reaction initiated by deprotonation at low temperature.
Journal ArticleDOI
Site-Selective C-H Functionalization-Sulfination Sequence to Access Aryl Sulfonamides.
TL;DR: An operationally simple one-pot palladium-catalyzed protocol introduces the sulfonyl group using sodium hydroxymethylsulfinate (Rongalite) as a source of SO22–.
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Exploiting Heavier Organochalcogen Compounds in Donor-Acceptor Cyclopropane Chemistry.
André U. Augustin,Daniel B. Werz +1 more
TL;DR: The use of these highly strained three-membered entities paved the way to innovative and origi... as mentioned in this paper, and the use of cyclopropanes has gained increased momentum over the past two decades.
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