Journal ArticleDOI
Nanopore-Supported Metal Nanocatalysts for Efficient Hydrogen Generation from Liquid-Phase Chemical Hydrogen Storage Materials
TLDR
The latest research progress in catalytic hydrogen production is summarized, by using metal nanocatalysts confined within diverse nanoporous materials, such as metal-organic frameworks, porous carbons, zeolites, mesoporous silica, and porous organic polymers.Abstract:
Hydrogen has emerged as an environmentally attractive fuel and a promising energy carrier for future applications to meet the ever-increasing energy challenges. The safe and efficient storage and release of hydrogen remain a bottleneck for realizing the upcoming hydrogen economy. Hydrogen storage based on liquid-phase chemical hydrogen storage materials is one of the most promising hydrogen storage techniques, which offers considerable potential for large-scale practical applications for its excellent safety, great convenience, and high efficiency. Recently, nanopore-supported metal nanocatalysts have stood out remarkably in boosting the field of liquid-phase chemical hydrogen storage. Herein, the latest research progress in catalytic hydrogen production is summarized, from liquid-phase chemical hydrogen storage materials, such as formic acid, ammonia borane, hydrous hydrazine, and sodium borohydride, by using metal nanocatalysts confined within diverse nanoporous materials, such as metal-organic frameworks, porous carbons, zeolites, mesoporous silica, and porous organic polymers. The state-of-the-art synthetic strategies and advanced characterizations for these nanocatalysts, as well as their catalytic performances in hydrogen generation, are presented. The limitation of each hydrogen storage system and future challenges and opportunities on this subject are also discussed. References in related fields are provided, and more developments and applications to achieve hydrogen energy will be inspired.read more
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Journal ArticleDOI
Recent developments of nanocatalyzed liquid-phase hydrogen generation
Changlong Wang,Didier Astruc +1 more
TL;DR: An overview of the recent achievements in nanocatalysis of hydrogen production from liquid-phase hydrogen storage materials including metal-boron hydrides, borane-nitrogen compounds, and liquid organic hydride is provided in this article.
Journal ArticleDOI
Interfacial sp C-O-Mo Hybridization Originated High-Current Density Hydrogen Evolution.
Yuan Yao,Yuhua Zhu,Chuanqi Pan,Chenyang Wang,Siyu Hu,Wen Xiao,Xiao Chi,Yarong Fang,Ji Yang,Hongtao Deng,Shengqiang Xiao,Junbo Li,Zhu Luo,Yanbing Guo +13 more
TL;DR: In this article, an original three-dimensional self-supporting graphdiyne/molybdenum oxide (GDY/MoO3) material for efficient hydrogen evolution reaction via a rational design of "sp C-O-Mo hybridization" on the interface.
Journal Article
Zeolite‐Encaged Pd‐Mn Nanocatalysts for CO2 Hydrogenation and Formic Acid Dehydrogenation
Sun Qiming,Benjamin Wj Chen,Ning Wang,He Qian,Albert M. Chang,Chia-Min Yang,Hiroyuki Asakura,Tsunehiro Tanaka,Max J. Hülsey,Wang Chi-Hwa,Jihong Yu,Yan Ning +11 more
Journal ArticleDOI
Hydrogen Generation upon Nanocatalyzed Hydrolysis of Hydrogen-Rich Boron Derivatives: Recent Developments.
TL;DR: Dramatic triple synergies between these nanocatalyst components have allowed hydrogen release within a few seconds under ambient conditions to inspire further nanoc atalyst design in various areas of hydrogen production.
Journal ArticleDOI
Emerging applications of zeolites in catalysis, separation and host–guest assembly
TL;DR: In this article, the authors focus on the advances in zeolite applications, including the catalytic production of hydrocarbons and oxygenates from non-petrochemical feedstocks, the efficient separation of hydrocarbon mixtures that are otherwise challenging, and host-guest assemblies with unprecedented physical properties.
References
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Journal ArticleDOI
Hydrogen-storage materials for mobile applications
TL;DR: Recent developments in the search for innovative materials with high hydrogen-storage capacity are presented.
Journal ArticleDOI
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Journal ArticleDOI
Alternative energy technologies
M. S. Dresselhaus,I. L. Thomas +1 more
TL;DR: Fossil fuels currently supply most of the world's energy needs, and however unacceptable their long-term consequences, the supplies are likely to remain adequate for the next few generations.
Journal ArticleDOI
Synthesis of metal-organic frameworks (MOFs): routes to various MOF topologies, morphologies, and composites.
Norbert Stock,Shyam Biswas +1 more
Journal ArticleDOI
Ultrahigh Porosity in Metal-Organic Frameworks
Hiroyasu Furukawa,Nakeun Ko,Yong Bok Go,Naoki Aratani,Sang Beom Choi,Eunwoo Choi,A. Oezguer Yazaydin,Randall Q. Snurr,Michael O'Keeffe,Jaheon Kim,Omar M. Yaghi +10 more
TL;DR: The synthesis of a MOF in which zinc centers are bridged with long, highly conjugated organic linkers, but in which the overall symmetry of the networks created prevents formation of interpenetrating networks is described.