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Novel processing route for the fabrication of bulk high-entropy metal diborides

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TLDR
In this article, a single high-entropy phase material with hexagonal structure is produced by a two-step processing method using self-propagating high-temperature synthesis (SHS).
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This article is published in Scripta Materialia.The article was published on 2019-01-01 and is currently open access. It has received 137 citations till now. The article focuses on the topics: Spark plasma sintering & Self-propagating high-temperature synthesis.

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High-entropy alloys

TL;DR: This Review discusses model high-entropy alloys with interesting properties, the physical mechanisms responsible for their behaviour and fruitful ways to probe and discover new materials in the vast compositional space that remains to be explored.
Journal ArticleDOI

Review of high entropy ceramics: design, synthesis, structure and properties

TL;DR: High entropy ceramics are novel materials with no less than four different cations or anions as mentioned in this paper, and they have recently generated significant interest with the publication of 70+ related papers since 2015.
Journal ArticleDOI

A high-entropy silicide: (Mo0.2Nb0.2Ta0.2Ti0.2W0.2)Si2

TL;DR: A high-entropy metal disilicide, (Mo 0.2Nb0.2Ta0.6222)Si2, has been successfully synthesized as discussed by the authors.
Journal ArticleDOI

High-entropy ceramics: Review of principles, production and applications

TL;DR: High-entropy ceramics with five or more cations have recently attracted significant attention due to their superior properties for various structural and functional applications as mentioned in this paper, and significant efforts were started to increase the entropy, minimize the Gibbs free energy, and achieve stable single-phase high-entropically stable ceramic films.
References
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VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data

TL;DR: VESTA has been upgraded to the latest version, VESTA 3, implementing new features including drawing the external mor­phology of crystals, and an extended bond-search algorithm to enable more sophisticated searches in complex molecules and cage-like structures.
Journal ArticleDOI

A critical review of high entropy alloys and related concepts

TL;DR: High entropy alloys (HEAs) are barely 12 years old as discussed by the authors, and the field has stimulated new ideas and inspired the exploration of the vast composition space offered by multi-principal element alloys.
Book

Thermochemical data of pure substances

Ihsan Barin
TL;DR: In this article, the first law of thermodynamics and the third law of Nernst heat theorem are used to construct tables of thermochemical data of pure substances, which are then used for thermodynamic calculations.
Journal ArticleDOI

High-entropy alloy: challenges and prospects

TL;DR: In this paper, a critical review of the recent studies aiming to address the fundamental issues related to phase formation in high-entropy alloys is provided, and novel properties of HEAs are also discussed, such as their excellent specific strength, superior mechanical performance at high temperatures, exceptional ductility and fracture toughness at cryogenic temperatures, superparamagnetism and superconductivity.
Journal ArticleDOI

Entropy-stabilized oxides

TL;DR: It is demonstrated beyond reasonable doubt that entropy predominates the thermodynamic landscape, and drives a reversible solid-state transformation between a multiphase and single-phase state.
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Frequently Asked Questions (10)
Q1. What are the contributions in "Dear editor, please find in the attached file our replies to the comments raised by the reviewer regarding our manuscript “novel processing route for the fabrication of bulk high-entropy metal diborides” by g. tallarita," ?

In this paper, a single high-entropy phase material with hexagonal structure is produced by a two-step processing method. 

In addition, when ceramic composites are synthesized, it is observed that stronger interfacial bonds are established between the fine grains of the different phases simultaneously formed in-situ, which lead to a reduction of the diffusion distances [24]. 

The strong interest in these materials stems from the improved thermal stability and strengthening they usually exhibit with respect to conventional alloys [3-5] 

B2 (1)The use of a slight excess of B (x=0.2) with respect to the stoichiometric value allows for, in agreement to previous studies related to the obtainment of individual metal diborides [17-18], the removal of oxide impurities initially present in the raw powders. 

On the basis of the results discussed in this work, it is possible to state the SHS method represents a suitable tool for obtaining powders to be processed by SPS for the fabrication of innovative high entropy ceramics. 

These aspects are also expected to play a beneficial role in promoting the atomic diffusion in SHS powders for the formation of the single phase HEBs during the SPS stage. 

On the basis of the results discussed in this work, it is possible to state the SHS method represents a suitable tool for obtaining powders to be processed by SPS for the fabrication of innovative high entropy ceramics. 

Of course, the potential of this HEB for industrial applications can be better defined when residual porosity of the bulk sample will be reduced, so that the mechanical properties and oxidation resistance could be correspondingly improved. 

Of course, the potential of this HEB for industrial applications can be better defined when residual porosity of the bulk sample will be reduced, so that the mechanical properties and oxidation resistance could be correspondingly improved. 

The major concern related to the previously mentioned fabrication methods is represented by the intense mechanical pre-treatment of the powder mixture requested to induce the formation of a single1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 653phase product during the subsequent densification stage.