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“One-pot” synthesis and shape control of ZnSe semiconductor nanocrystals in liquid paraffin

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TLDR
In this paper, a "one-pot" strategy for synthesizing ZnSe nanocrystals (NCs) in liquid paraffin was proposed, which avoided the injection of Se source at high temperature.
Abstract
In this paper, we demonstrated a “one-pot” strategy for synthesizing ZnSe nanocrystals (NCs) in liquid paraffin. All materials, including Zn source, Se source, and ligand, were mixed in liquid paraffin beforehand, which avoided the injection of Se source at high temperature. The resultant ZnSe NCs possessed high photoluminescence quantum yields and narrow size distribution. Moreover, the size, shape, and crystal phase of NCs were controllable by altering the experimental variables, such as precursor concentration, Zn:Se molar ratio, and heating rate. Because the raw materials used here were low-cost and environmentally friendly, this “one-pot” synthetic protocol would facilitate the commercial scale synthesis of high-quality ZnSe NCs.

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The heat-up synthesis of colloidal nanocrystals

TL;DR: In this class of synthesis precursors are heated within a reaction medium to induce a chemical reaction that yields monomer for nucleation and growth as discussed by the authors, which is a reliable means to achieve high quality nanomaterials on large scales with little or no batch-to-batch variation.
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Synthesis of Alloyed ZnSeTe Quantum Dots as Bright, Color-Pure Blue Emitters

TL;DR: In this paper, the synthesis of non-Cd, ZnSe-based QDs with binary and ternary compositions toward blue photoluminescence (PL) was explored.
Journal ArticleDOI

Heavy-Metal-Free Colloidal Semiconductor Nanorods: Recent Advances and Future Perspectives

TL;DR: The main growth mechanisms of heavy-metal-free colloidal semiconductor NRs are first elaborated, including anisotropic-controlled growth, oriented attachment, solution-liquid-solid method, and cation exchange, followed by highlighted practical applications in terms of photocatalysis, photodetectors, solar cells, and biomedicine.
Journal ArticleDOI

Chemical Synthesis, Structural Characterization, Optical Properties, and Photocatalytic Activity of Ultrathin ZnSe Nanorods

TL;DR: It was found that the ultrathin nanorods possessed better photocatalytic activities than conventional ones and exhibited a remarkable quantum size effect in terms of their optical properties.
Journal ArticleDOI

Blue quantum dot-based electroluminescent light-emitting diodes

TL;DR: In this article, a review of the recent research progress in blue QD-LEDs, including Cd-based blue QDs, perovskite-based LEDs (PeLEDs), and heavy-metal-free blue LEDs (HMLF LEDs), is presented.
References
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Journal ArticleDOI

Semiconductor Clusters, Nanocrystals, and Quantum Dots

TL;DR: In this article, the authors focus on the properties of quantum dots and their ability to join the dots into complex assemblies creates many opportunities for scientific discovery, such as the ability of joining the dots to complex assemblies.
Journal ArticleDOI

Synthesis and characterization of nearly monodisperse CdE (E = sulfur, selenium, tellurium) semiconductor nanocrystallites

TL;DR: In this paper, a simple route to the production of high-quality CdE (E=S, Se, Te) semiconductor nanocrystallites is presented, based on pyrolysis of organometallic reagents by injection into a hot coordinating solvent.
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Quantum Dots for Live Cells, in Vivo Imaging, and Diagnostics

TL;DR: The new generations of qdots have far-reaching potential for the study of intracellular processes at the single-molecule level, high-resolution cellular imaging, long-term in vivo observation of cell trafficking, tumor targeting, and diagnostics.
Journal ArticleDOI

Quantum Dot Bioconjugates for Ultrasensitive Nonisotopic Detection

TL;DR: Highly luminescent semiconductor quantum dots (zinc sulfide-capped cadmium selenide) have been covalently coupled to biomolecules for use in ultrasensitive biological detection and these nanometer-sized conjugates are water-soluble and biocompatible.
Journal ArticleDOI

Hybrid Nanorod-Polymer Solar Cells

TL;DR: It is demonstrated that semiconductor nanorods can be used to fabricate readily processed and efficient hybrid solar cells together with polymers and Tuning the band gap by altering the nanorod radius enabled us to optimize the overlap between the absorption spectrum of the cell and the solar emission spectrum.
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