Journal ArticleDOI
Progress in the mitsunobu reaction. a review
TLDR
A review of progress in the MITSUNOBU this article reaction can be found in this article, with a focus on the MIT SUNOBU reaction and a review of the progress.About:
This article is published in Organic Preparations and Procedures International.The article was published on 1996-04-01. It has received 373 citations till now. The article focuses on the topics: Mitsunobu reaction.read more
Citations
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The teraton challenge. A review of fixation and transformation of carbon dioxide
TL;DR: In this paper, the authors present a review of CO2, its synthetic reactions and their possible role in future CO2 mitigation schemes that have to match the scale of man-made CO2 in the atmosphere, which rapidly approaches 1 teraton.
Journal ArticleDOI
Key green chemistry research areas—a perspective from pharmaceutical manufacturers
David J. C. Constable,Peter J. Dunn,John D. Hayler,Guy R. Humphrey,Johnnie L. Leazer,Russell J. Linderman,Kurt T. Lorenz,Julie B. Manley,Bruce A. Pearlman,Andrew S. Wells,Aleksey Zaks,Tony Y. Zhang +11 more
TL;DR: An assessment of the current state of the art in green chemistry and green engineering areas and to highlight areas for future improvement are provided.
Journal ArticleDOI
Mitsunobu and Related Reactions: Advances and Applications
TL;DR: This review concludes that Etherification without Cyclization and N-Alkylation should be considered as separate science, and the proposed treatment of Etherification with Cyclization as a separate science should be reconsidered.
Journal ArticleDOI
Aspects of carbon dioxide utilization
TL;DR: In this paper, the production of carbon dioxide with metal compounds as catalysts has been studied and further development of these production processes is expected, especially the productions of formic acids, formic acid methyl esters, formamides, methanol, dimethyl carbonate and urethanes with a dialkyltin catalyst.
References
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Journal ArticleDOI
Acidity of benzoylcarbamates in dimethyl sulfoxide. Confirmation of mixed N/O alkylation in the Mitsunobu reaction
Ilmar A. Koppel,Juta Koppel,Ivar Koppel,Ivo Leito,Viljar Pihl,Annelie Wallin,Leif Grehn,Ulf Ragnarsson +7 more
TL;DR: In this paper, 17 benzoyl-, 4methoxybenzoyl- and 4-nitrobenzoys-carbamates have been synthesized via their corresponding isocyanates and their acidities determined in dimethyl sulfoxide solution.
Journal ArticleDOI
Synthesis of aryl d-gluco- and d-galacto-pyranosides and 1-O-acyl-d-gluco- and -d-gluco-pyranoses exploiting the mitsunobu reaction. Influence of the pKa of the acid on the stereoselectivity of the reaction
TL;DR: Glycosids derived from three pesticides, 2- tert -butyl-2,4-dinitrophenol,2,6-dibromo-4-cyanophenol, and 5-(2, 4-dichlorophenoxy)-2-nitrobenzoic acid, were synthesized from 2,3,4, 6-tetra-O -chloroacetyl-d -gluco- and - d -galactopyranose by use of the Mitsunobu reaction as mentioned in this paper.
Journal ArticleDOI
The Synthesis of Boronolide
Charles W. Jefford,M. C. Moulin +1 more
TL;DR: In this article, Boronolide was prepared in six steps in 4.4 hours using acrolein dimer 6 and 1-(trimethyl-silyl)hex-1-yne.
Journal ArticleDOI
Synthesis of combretastatin D-2. An efficient route to caffrane macrolactones
TL;DR: Combretastatin D-2, (1) was synthesized via a 10-step sequence as mentioned in this paper, which was performed on saturated substrate 12 in high yield and the double bond was established via dehalogenation of intermediate 15.
Journal ArticleDOI
Stereocontrolled syntheses of some conformationally restricted analogs of serotonin
A. Ghosh,Wuyi Wang,Jeremiah P. Freeman,John S. Althaust,Philip F. VonVoigtlander,Terrence A. Scahill,Stephen A. Mizsak,Jacob Szmuszkovicz +7 more
TL;DR: In this paper, the synthesis of synthesized serotonin analogs 2 and 3 is described, including a case of retention in the Mitsunobu reaction, and an unusual stereoselectivity in a reductive amination sequence is also described.
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