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Journal ArticleDOI

Stimuli-responsive molecular brushes

TLDR
In this paper, the authors review the general aspects of molecular brushes and polymeric responsive systems and highlight the rational approaches to induce stimuli-responsiveness in molecular brush systems, which are unique for molecular brushes since these conformational changes can be restricted to a single molecule.
About
This article is published in Progress in Polymer Science.The article was published on 2010-01-01. It has received 592 citations till now. The article focuses on the topics: Polymer brush.

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Book ChapterDOI

Copper-Mediated Atom Transfer Radical Polymerization

TL;DR: In this article, the evolution and the current status of copper-mediated atom transfer radical polymerization (ATRP) are summarized and discussed sequentially with the latest more environmentally benign procedures that only require ppm levels of catalyst.
Journal ArticleDOI

Recent developments towards performance-enhancing lignin-based polymers

TL;DR: In this paper, a review of developments in the translation of lignin into value-added macromolecular components are discussed with a focus on applications and key hurdles and future opportunities in Lignin valorization are explored.
Journal ArticleDOI

Behavior of thermosensitive graft copolymer with aromatic polyester backbone and poly-2-ethyl-2-oxazoline side chains in aqueous solutions

TL;DR: In this article, two graft copolymer samples which differed in grafting density (0.5 and 0.7) were studied using dynamic and static light scattering and turbidimetry in aqueous solutions at concentration 0.0053g cm−3.
Journal ArticleDOI

Tunable assembly and disassembly of responsive supramolecular polymer brushes

TL;DR: In this paper, the authors reported the synthesis and assembly of light-responsive supramolecular polymer brushes based on the host-guest interaction between β-cyclodextrin (β-CD) on star-like side chains and azobenzene groups on a polymer backbone.
Journal ArticleDOI

Confined Microenvironments from Thermoresponsive Dendronized Polymers.

TL;DR: Formation of confined microenvironments from stimuli-responsive dendronized polymers carrying densely dendritic oligoethylene glycols (OEGs) moieties in their pendants is presented and the switchable encapsulation and release of guests can be greatly enhanced when these dendrons are used as major constituents for fabricating bulk hydrogels or nanogels, which provide a higher-level confinement.
References
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Journal ArticleDOI

Living free-radical polymerization by reversible addition - Fragmentation chain transfer: The RAFT process

TL;DR: The authors proposed a reversible additive-fragmentation chain transfer (RAFT) method for living free-radical polymerization, which can be used with a wide range of monomers and reaction conditions and in each case it provides controlled molecular weight polymers with very narrow polydispersities.
Journal ArticleDOI

Environment-sensitive hydrogels for drug delivery

TL;DR: Development of environmentally sensitive hydrogels with a wide array of desirable properties can be made is a formidable challenge, however, if the achievements of the past can be extrapolated into the future, it is highly likely that responsive hydrogelWith such properties can been made.
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