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Journal ArticleDOI

Stimuli-responsive molecular brushes

TLDR
In this paper, the authors review the general aspects of molecular brushes and polymeric responsive systems and highlight the rational approaches to induce stimuli-responsiveness in molecular brush systems, which are unique for molecular brushes since these conformational changes can be restricted to a single molecule.
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This article is published in Progress in Polymer Science.The article was published on 2010-01-01. It has received 592 citations till now. The article focuses on the topics: Polymer brush.

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Atom Transfer Radical Polymerization (ATRP): Current Status and Future Perspectives

TL;DR: The current status and future perspectives in atom transfer radical polymerization (ATRP) are presented in this paper, with a special emphasis on mechanistic understanding of ATRP, recent synthetic and process development, and new controlled polymer architectures enabled by ATRP.
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Design and Preparation of Porous Polymers

TL;DR: This work presents a new mesoporous composite material suitable for high-performance liquid chromatography and shows good chiral recognition ability and high uniformity in various racemates.
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Design of polymeric nanoparticles for biomedical delivery applications

TL;DR: This tutorial review highlights the importance of well-defined chemistries, with detailed ties to specific biological hurdles and opportunities, in the design of nanostructures for various biomedical delivery applications.
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New directions in thermoresponsive polymers.

TL;DR: By highlighting recent examples of newly developed thermoresponsive polymer systems, it is hoped to promote the development of new generations of smart materials.
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Macromolecular Engineering by Atom Transfer Radical Polymerization

TL;DR: This Perspective presents recent advances in macromolecular engineering enabled by ATRP with emphasis on various catalytic/initiation systems that use parts-per-million concentrations of Cu catalysts and can be run in environmentally friendly media, e.g., water.
References
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Journal ArticleDOI

Measuring Molecular Weight by Atomic Force Microscopy

TL;DR: Absolute-molecular-weight distribution of cylindrical brush molecules were determined using a combination of the Langmuir Blodget (LB) technique and Atomic Force Microscopy (AFM).

Student Research Award in the Doctoral Degree Candidate Category, 7th Biomaterials World Congress, Sydney, Australia, May 16 -21, 2004 Novel cell patterning using microheater-controlled thermoresponsive plasma films

TL;DR: In this paper, a novel approach is reported for cell patterning based on addressable microheaters and a poly(N-isopropyl acrylamide) (pNIPAM) themoresponsive coating.
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Synthesis and Self-Assembly of Coil−Rod Double Hydrophilic Diblock Copolymer with Dually Responsive Asymmetric Centipede-Shaped Polymer Brush as the Rod Segment

TL;DR: In this article, the synthesis and self-assembly of a double hydrophilic diblock copolymer with pH-and thermo-responsive asymmetric centipede-shaped polymer brush as the rod segment via a combination of atom transfer radical polymerization (ATRP) and click chemistry was reported.
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New Polymer Chain Architecture: Synthesis and Characterization of Star Polymers with Comb Polystyrene Branches

TL;DR: In this paper, a star-like comb polystyrenes (star polymers with four and five arms constituted of PS combs) have been synthesized based on the highly selective coupling reaction of living polystyryllithium onto poly(chloroethyl vinyl ether) chains with a starlike chain architecture.
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Microchannel DNA Sequencing Matrices with a Thermally Controlled “Viscosity Switch”

TL;DR: The reproducible synthesis, precise characterization, and excellent DNA sequencing performance of high molar mass, thermoresponsive polymer matrices that exhibit a reversible, temperature-controlled "viscosity switch" that decouples matrix loading and sieving properties, enabling acceleration of microchannel flow by 3 orders of magnitude.
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