Journal ArticleDOI
Synthesis and Stabilization of Supported Metal Catalysts by Atomic Layer Deposition
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TLDR
Using methanol decomposition and oxidative dehydrogenation of ethane as probe reactions, it is demonstrated that selectively blocking low coordination metal sites by oxide overcoats can provide another strategy to enhance both the durability and selectivity of metal catalysts.Abstract:
Supported metal nanoparticles are among the most important cata-lysts for many practical reactions, including petroleum refining, automobile exhaust treatment, and Fischer–Tropsch synthesis. The catalytic performance strongly depends on the size, composition, and structure of the metal nanoparticles, as well as the underlying support. Scientists have used conventional synthesis methods including impregnation, ion exchange, and deposition–precipitation to control and tune these factors, to establish structure–performance relationships, and to develop better catalysts. Meanwhile, chemists have improved the stability of metal nanoparticles against sintering by the application of protective layers, such as polymers and oxides that encapsulate the metal particle. This often leads to decreased catalytic activity due to a lack of precise control over the thickness of the protective layer.A promising method of catalyst synthesis is atomic layer deposition (ALD). ALD is a variation on chemical vapor deposition in ...read more
Citations
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Single-Atom Pd₁/Graphene Catalyst Achieved by Atomic Layer Deposition: Remarkable Performance in Selective Hydrogenation of 1,3-Butadiene.
TL;DR: In this article, the atomically dispersed Pd on graphene can be fabricated using the atomic layer deposition technique, and the single-atom Pd1/graphene catalyst showed about 100% butenes selectivity at 95% conversion at a mild reaction condition of about 50 °C, likely due to the changes of 1,3-butadiene adsorption mode and enhanced steric effect on the isolated Pd atoms.
Journal ArticleDOI
Catalyst Design with Atomic Layer Deposition
Brandon J. O'Neill,Brandon J. O'Neill,David H. K. Jackson,Jechan Lee,Christian P. Canlas,Peter C. Stair,Christopher L. Marshall,Jeffrey W. Elam,Thomas F. Kuech,James A. Dumesic,George W. Huber +10 more
TL;DR: Atomic layer deposition (ALD) has emerged as an interesting tool for the atomically precise design and synthesis of catalytic materials as mentioned in this paper, which can be used to elucidate reaction mechanisms and catalyst structure-property relationships by creating materials with a controlled distribution of size, composition, and active site.
Journal ArticleDOI
Carbon-Supported Single Atom Catalysts for Electrochemical Energy Conversion and Storage.
TL;DR: The leading strategies for the preparation of single atoms of select transition metals supported on carbon substrates are summarized, and the electrocatalytic performance of the resulting samples for the various reactions is discussed.
Journal ArticleDOI
Atomic site electrocatalysts for water splitting, oxygen reduction and selective oxidation.
TL;DR: This review presents a systematic review on the fabrication routes of ASCs followed by an overview of some new and effective characterization methods to precisely probe the atomic structure and discusses the challenges and opportunities on the further development of more selective, active, stable and less expensive ASCs.
Journal ArticleDOI
Single-atom catalysis in advanced oxidation processes for environmental remediation.
TL;DR: In this paper, the authors highlight the synthetic strategies, characterisation, and computation of carbon-based SACs, and for the first time, showcase their innovative applications in advanced oxidation processes.
References
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Journal ArticleDOI
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TL;DR: The literature treating mechanisms of catalyst deactivation is reviewed in this paper, which can be classified into six distinct types: (i) poisoning, (ii) fouling, (iii) thermal degradation, (iv) vapor compound formation accompanied by transport, (v) vapor solid and/or solid solid reactions, and (vi) attrition/crushing.
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The impact of nanoscience on heterogeneous catalysis
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Surface chemistry of atomic layer deposition: A case study for the trimethylaluminum/water process
TL;DR: In this paper, the surface chemistry of the trimethylaluminum/water ALD process is reviewed, with an aim to combine the information obtained in different types of investigations, such as growth experiments on flat substrates and reaction chemistry investigation on high-surface-area materials.
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Atomic-scale imaging of carbon nanofibre growth
Stig Helveg,Carlos López-Cartes,Carlos López-Cartes,Jens Sehested,Poul L. Hansen,Clausen Bjerne Steffen,Jens R. Rostrup-Nielsen,Frank Abild-Pedersen,Jens K. Nørskov +8 more
TL;DR: Time-resolved, high-resolution in situ transmission electron microscope observations of the formation of carbon nanofibres from methane decomposition over supported nickel nanocrystals show that metallic step edges act as spatiotemporal dynamic growth sites and may be important for understanding other types of catalytic reactions and nanomaterial syntheses.