Journal ArticleDOI
Synthesis,TG, DSC and infrared spectral study of NiMn2(C4H4O4)3·6N2H4
TLDR
Nickel manganese succinato-hydrazinate (NiMn2(C4H4O4)3·6N2H4) has been synthesized for the first time by a novel precursor technique and characterized by IR, AAS and XRD as discussed by the authors.Abstract:
Nickel manganese succinato-hydrazinate (NiMn2(C4H4O4)3·6N2H4), has been synthesized for the first time by a novel precursor technique and characterized by IR, AAS and XRD. Thermal decomposition of the compound was studied from room temperature (rT) to 800°C by differential scanning calorimetry (DSC) and thermogravimetric (TG) analysis besides isothermal mass loss studies. The compound was found to decompose autocatalytically, once ignited. TG-DSC shows two steps decomposition i.e. dehydrazination followed by decarboxylation. The infrared spectral studies show the N–N stretching frequency at 972 cm–1 suggesting a bidentate bridging structure of hydrazine molecule in (NiMn2(C4H4O4)3·6N2H4).read more
Citations
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Effect of alkali metal doping on the properties and crystalline perfection of bis(thiourea)zinc(II) chloride crystals
TL;DR: In this article, the effect of magnesium doping on the properties of bis(thiourea)zinc(II) chloride (BTZC) crystals has been described.
Journal ArticleDOI
The growth and characterization of a metal organic crystal, potassium thiourea thiocyanide
TL;DR: The growth and characterization of a new non-linear organometallic crystal, potassium thiourea thiocyanide (PTT) is reported in this article.The growth of single crystals was accomplished by the slow evaporation solution growth method.
Journal ArticleDOI
Synthesis and characterization of nanosize nickel-doped cobalt ferrite obtained by precursor combustion method
TL;DR: In this article, the precursors of metal fumarato-hydrazinate have been employed to yield the nanosized spinel ferrite, which decomposes autocatalytically after ignition to give the monophasic nanocrystalline ferrite.
Journal ArticleDOI
Thermal properties of solid complexes with biologically important heterocyclic ligands
L’. Lajdová,E. Jóna,S. Šnircová,J. Miklovič,P. Segl’a,M. Pajtášová,D. Ondrušová,S. C. Mojumdar,S. C. Mojumdar +8 more
TL;DR: In this article, the authors applied DTG to investigate the thermal behavior of the compounds Cu(2-Clbz), 2-Brbz, 2-denia and 2-H2O.
Journal ArticleDOI
Synthesis, thermo-analytical and IR spectral studies of hydrazinated mixed metal carboxylates: A single source precursor to nanosize mixed metal oxides
U. B. Gawas,V. M. S. Verenkar +1 more
TL;DR: In this paper, a series of hydrazinated mixed nickel manganese zinc ferrous hydrazine fumarate complexes were synthesized from aqueous mixed metal chloride solutions and sodium fumararate-hydrazine hydrate mixture.
References
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