Journal ArticleDOI
The asymmetric intramolecular Heck reaction in natural product total synthesis.
Amy B. Dounay,Larry E. Overman +1 more
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This article is published in Chemical Reviews.The article was published on 2003-07-08. It has received 1247 citations till now. The article focuses on the topics: Heck reaction & Total synthesis.read more
Citations
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Journal ArticleDOI
Mizoroki-Heck cross-coupling of acrylate derivatives with aryl halides catalyzed by palladate pre-catalysts
Mohammad Shahidul Islam,Fady Nahra,Fady Nahra,Nikolaos V. Tzouras,Assem Barakat,Catherine S. J. Cazin,Steven P. Nolan,Steven P. Nolan,Abdullah Mohammed Al-Majid +8 more
TL;DR: In this article, the effects of solvent, catalyst loading, temperature and bases on the reaction outcome have been investigated and various coupling partners were tolerated under the optimal reaction conditions catalyzed by palladate 1.
Journal ArticleDOI
A survey of synthetic routes towards 2-azaanthraquinones
Journal ArticleDOI
Facile synthesis of nanostructured Ni-Co/ZnO material: An efficient and inexpensive catalyst for Heck reactions under ligand-free conditions
Digambar B. Bankar,K.G. Kanade,Ranjit R. Hawaldar,Sudhir S. Arbuj,Manish Shinde,Shrikant P. Takle,Dinesh Amalnerkar,Santosh T. Shinde +7 more
TL;DR: In this paper, a simple, efficient and economically viable method for the Heck reaction has been accomplished in the absence of phosphine ligand, using nanostructured Ni-Co/ZnO material as a heterogeneous catalyst in a DMF/H2O solvent system.
Journal ArticleDOI
Comparison of Imine to Olefin Insertion Reactions: Generation of Five- and Six-Membered Lactams via a Nickel-Mediated CO, Olefin, CO, Imine Insertion Cascade
Jason L. Davis,Bruce A. Arndtsen +1 more
TL;DR: Cationic nickel complexes of the form L2Ni(CH3),RN═C(H)R)+ (L2 = bidentate nitrogen donor) have been probed for their ability to mediate olefin and imine migratory insertion reactions as discussed by the authors.
References
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BookDOI
Metal-catalyzed cross-coupling reactions
TL;DR: In this paper, the authors present an approach to the formation of C-X (X = N, O, S) bonds in metal-catalyzed cross-coupling reactions.
Journal ArticleDOI
The heck reaction as a sharpening stone of palladium catalysis.
TL;DR: s, or keywords if they used Heck-type chemistry in their syntheses, because it became one of basic tools of organic preparations, a natural way to make organic preparations.
Book
Catalytic Asymmetric Synthesis
TL;DR: Asymmetric Hydrogenation (T. Ohkuma, et al. as discussed by the authors ), asymmetric carbon-Carbon Bond-Forming Reactions (K. Nozaki & I. Negishi). Asymmetric Addition and Insertion Reactions of Catalytically-Generated Metal Carbenes (M. O'Donnell), and asymptotic phase-transfer Reactions.
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Richard F. Heck,J. P. Nolley +1 more