Journal ArticleDOI
The asymmetric intramolecular Heck reaction in natural product total synthesis.
Amy B. Dounay,Larry E. Overman +1 more
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This article is published in Chemical Reviews.The article was published on 2003-07-08. It has received 1247 citations till now. The article focuses on the topics: Heck reaction & Total synthesis.read more
Citations
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Sequential catalysis for stereoselective synthesis of complex polyketides
TL;DR: This review presents recent advances in sequential catalytic methods developed in this group for the rapid and stereoselective synthesis of key structural features of complex polyketides, including a novel domino reaction, based on a combination of a nucleophilic addition and a Tsuji-Trost reaction.
Journal ArticleDOI
A palladium-catalyzed carbo-oxygenation: the bielschowskysin case.
TL;DR: An asymmetric synthesis of an advanced tetracyclic intermediate toward the synthesis of bielschowskysin is described and macrocyclization under Heck conditions led to an unprecedented carbo-oxygenation of a 1,1-disubstituted double bond.
Journal ArticleDOI
Dinuclear Pd(II)–NHC complex derived from proline and its application toward Mizoroki–Heck reaction performed in water
Ming‐Tao Ma,Jian‐Mei Lu +1 more
TL;DR: A dinuclear Pd(II)-N-heterocyclic carbene complex derived from proline was successfully synthesized and its structure was confirmed unambiguously by X-ray single-crystal diffraction.
Journal ArticleDOI
Palladium-catalyzed cross-coupling of α-bromocarbonyls and allylic alcohols for the synthesis of α-aryl dicarbonyl compounds
Yang Yu,Uttam K. Tambar +1 more
TL;DR: A palladium-catalyzed coupling of α-bromocarbonyl compounds and allylic alcohols has been developed for the generation of acyclic aryl-substituted dicarbonyL compounds.
Journal ArticleDOI
Progress on Catalytic Systems Used in Click Polymerization.
TL;DR: The vital employment of catalysts is reviewed and their developments from innovative discoveries to the eminent position are outlined and the challenges and perspectives in this area are briefly discussed.
References
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BookDOI
Metal-catalyzed cross-coupling reactions
TL;DR: In this paper, the authors present an approach to the formation of C-X (X = N, O, S) bonds in metal-catalyzed cross-coupling reactions.
Journal ArticleDOI
The heck reaction as a sharpening stone of palladium catalysis.
TL;DR: s, or keywords if they used Heck-type chemistry in their syntheses, because it became one of basic tools of organic preparations, a natural way to make organic preparations.
Book
Catalytic Asymmetric Synthesis
TL;DR: Asymmetric Hydrogenation (T. Ohkuma, et al. as discussed by the authors ), asymmetric carbon-Carbon Bond-Forming Reactions (K. Nozaki & I. Negishi). Asymmetric Addition and Insertion Reactions of Catalytically-Generated Metal Carbenes (M. O'Donnell), and asymptotic phase-transfer Reactions.
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Richard F. Heck,J. P. Nolley +1 more