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The MN+1AXN phases: A new class of solids

Michel W. Barsoum
- 01 Jan 2000 - 
- Vol. 28, Iss: 28, pp 201-281
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This article is published in Progress in Solid State Chemistry.The article was published on 2000-01-01. It has received 2879 citations till now.

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Two‐Dimensional Nanocrystals Produced by Exfoliation of Ti 3 AlC 2

TL;DR: 2D nanosheets, composed of a few Ti 3 C 2 layers and conical scrolls, produced by the room temperature exfoliation of Ti 3 AlC 2 in hydrofl uoric acid are reported, which opens a door to the synthesis of a large number of other 2D crystals.
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25th Anniversary Article: MXenes: A New Family of Two‐Dimensional Materials

TL;DR: In this article, a new family of two-dimensional early transition metal carbides and carbonitrides, called MXenes, was discovered and a detailed outlook for future research on MXenes is also presented.
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Recent Advances in Ultrathin Two-Dimensional Nanomaterials

TL;DR: The unique advances on ultrathin 2D nanomaterials are introduced, followed by the description of their composition and crystal structures, and the assortments of their synthetic methods are summarized.
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Two-dimensional transition metal carbides.

TL;DR: Evidence is presented for the exfoliation of the following MAX phases by the simple immersion of their powders, at room temperature, in HF of varying concentrations for times varying between 10 and 72 h followed by sonication.
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Guidelines for Synthesis and Processing of Two-Dimensional Titanium Carbide (Ti3C2Tx MXene)

TL;DR: Two-dimensional transition metal carbides, carbonitrides, and nitrides (MXenes) were discovered in 2011 and more than 20 different compositions have been synthesized by the selective etching of MAX phase and other precursors and many more theoretically predicted as mentioned in this paper.
References
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Journal ArticleDOI

Synthesis and Characterization of a Remarkable Ceramic: Ti3SiC2

TL;DR: In this paper, a polycrystalline bulk sample of Ti sub 3, SiC sub 2 was fabricated by reactively hot-pressing Ti, graphite, and SiC powders at 40 MPa and 1,600 C for 4 h.
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Synthesis and Characterization of Ti3AlC2

TL;DR: In this article, the authors fabricated polycrystalline bulk samples of Ti 3 Al 1.1 C 1.8 by reactively hot isostatically pressing a mixture of titanium, graphite, and Al 4 C 3 powders at a pressure of 70 MPa and temperature of 1400°C for 16 h.
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Layered machinable ceramics for high temperature applications

TL;DR: In this paper, the authors reported on the fabrication and characterization of a layered ternary compound Ti{sub 3}SiC{sub 2], which was found to combine many of the best attributes of metals and ceramics.
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Localized vibrational modes in metallic solids

TL;DR: In this paper, the authors reported the observation of local modes in La-filled skutterdite antimonides, using heat capacity, elastic constant and inelastic neutron scattering measurements.
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Processing and characterization of Ti 2 AlC, Ti 2 AlN, and Ti 2 AlC 0.5 N 0.5

TL;DR: In this article, the authors report on the fabrication and characterization of Ti2AlC, Al4C3 graphite, and/or AlN powders for 15 hours at 1300 °C and 30 hours at 1000 °C, respectively.
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