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Journal ArticleDOI

The rise of graphene

Andre K. Geim, +1 more
- 01 Mar 2007 - 
- Vol. 6, Iss: 3, pp 183-191
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TLDR
Owing to its unusual electronic spectrum, graphene has led to the emergence of a new paradigm of 'relativistic' condensed-matter physics, where quantum relativistic phenomena can now be mimicked and tested in table-top experiments.
Abstract
Graphene is a rapidly rising star on the horizon of materials science and condensed-matter physics. This strictly two-dimensional material exhibits exceptionally high crystal and electronic quality, and, despite its short history, has already revealed a cornucopia of new physics and potential applications, which are briefly discussed here. Whereas one can be certain of the realness of applications only when commercial products appear, graphene no longer requires any further proof of its importance in terms of fundamental physics. Owing to its unusual electronic spectrum, graphene has led to the emergence of a new paradigm of 'relativistic' condensed-matter physics, where quantum relativistic phenomena, some of which are unobservable in high-energy physics, can now be mimicked and tested in table-top experiments. More generally, graphene represents a conceptually new class of materials that are only one atom thick, and, on this basis, offers new inroads into low-dimensional physics that has never ceased to surprise and continues to provide a fertile ground for applications.

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Citations
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Journal ArticleDOI

The electronic properties of graphene

TL;DR: In this paper, the basic theoretical aspects of graphene, a one-atom-thick allotrope of carbon, with unusual two-dimensional Dirac-like electronic excitations, are discussed.
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Graphene: Status and Prospects

TL;DR: This review analyzes recent trends in graphene research and applications, and attempts to identify future directions in which the field is likely to develop.
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Superior Thermal Conductivity of Single-Layer Graphene

TL;DR: The extremely high value of the thermal conductivity suggests that graphene can outperform carbon nanotubes in heat conduction and establishes graphene as an excellent material for thermal management.
Journal ArticleDOI

Large-Area Synthesis of High-Quality and Uniform Graphene Films on Copper Foils

TL;DR: It is shown that graphene grows in a self-limiting way on copper films as large-area sheets (one square centimeter) from methane through a chemical vapor deposition process, and graphene film transfer processes to arbitrary substrates showed electron mobilities as high as 4050 square centimeters per volt per second at room temperature.
Journal ArticleDOI

The chemistry of graphene oxide

TL;DR: This review will be of value to synthetic chemists interested in this emerging field of materials science, as well as those investigating applications of graphene who would find a more thorough treatment of the chemistry of graphene oxide useful in understanding the scope and limitations of current approaches which utilize this material.
References
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Journal ArticleDOI

Electronic properties of disordered two-dimensional carbon

TL;DR: In this article, the effects of localized (impurities or vacancies) and extended (edges or grain boundaries) defects on the electronic and transport properties of graphene are analyzed in a self-consistent way.
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Unconventional Integer Quantum Hall Effect in Graphene

TL;DR: It is demonstrated that monolayer graphite films have quasiparticle excitations that can be described by (2+1)-dimensional Dirac theory, which produces an unconventional form of the quantized Hall conductivity sigma(xy) = -(2e2/h)(2n+1) with n = 0, 1, ..., which notably distinguishes graphene from other materials where the integer quantum Hall effect was observed.
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Crystalline Order in Two Dimensions

TL;DR: In this article, it was shown that the Fourier component of the density must vanish in the thermodynamic limit, provided that the pair potential is in equilibrium in a parallelogram box.
Journal ArticleDOI

Asymmetry gap in the electronic band structure of bilayer graphene

TL;DR: In this paper, a tight-binding model is used to calculate the band structure of bilayer graphene in the presence of a potential difference between the layers that opens a gap between the conduction and valence bands.
Journal ArticleDOI

Bipolar supercurrent in graphene

TL;DR: Light is shed on the special role of time reversal symmetry in graphene, and phase coherent electronic transport at the Dirac point is demonstrated, finding that not only the normal state conductance of graphene is finite, but also a finite supercurrent can flow at zero charge density.
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How thick is a graphene sheet?

More generally, graphene represents a conceptually new class of materials that are only one atom thick, and, on this basis, offers new inroads into low-dimensional physics that has never ceased to surprise and continues to provide a fertile ground for applications.