scispace - formally typeset
Journal ArticleDOI

Water-Soluble Nonconjugated Polymer Nanoparticles with Strong Fluorescence Emission for Selective and Sensitive Detection of Nitro-Explosive Picric Acid in Aqueous Medium

Reads0
Chats0
TLDR
Water-soluble nonconjugated polymer nanoparticles (PNPs) with strong fluorescence emission were prepared from hyperbranched poly(ethylenimine) and d-glucose via Schiff base reaction and self-assembly and developed as a fluorescent probe for fast, selective, and sensitive detection of nitro-explosive picric acid in aqueous medium.
Abstract
Water-soluble nonconjugated polymer nanoparticles (PNPs) with strong fluorescence emission were prepared from hyperbranched poly(ethylenimine) (PEI) and d-glucose via Schiff base reaction and self-assembly in aqueous phase. Preparation of the PEI–d-glucose (PEI-G) PNPs was facile (one-pot reaction) and environmentally friendly under mild conditions. Also, PEI-G PNPs showed a high fluorescence quantum yield in aqueous solution, and the fluorescence properties (such as concentration- and solvent-dependent fluorescence) and origin of intrinsic fluorescence were investigated and discussed. PEI-G PNPs were then used to develop a fluorescent probe for fast, selective, and sensitive detection of nitro-explosive picric acid (PA) in aqueous medium, because the fluorescence can be easily quenched by PA whereas other nitro-explosives and structurally similar compounds only caused negligible quenching. A wide linear range (0.05–70 μM) and a low detection limit (26 nM) were obtained. The fluorescence quenching mechani...

read more

Citations
More filters
Journal ArticleDOI

Inner filter effect-based fluorescent sensing systems: A review.

TL;DR: The present review for the first time introduces the state of the art in the progress of the IFE-based fluorescent sensing systems, including sensing strategy, essential conditions, materials option, and their applications for the detection of various target analytes, e.g., ionic species, small molecules, and macromolecules.
Journal ArticleDOI

Conversion of Carbon Dots from Fluorescence to Ultralong Room-Temperature Phosphorescence by Heating for Security Applications

TL;DR: F-CDs, prepared with a simple heating treatment from ethylenediamine and phosphoric acid, are found to produce unexpected ultralong room-temperature phosphorescence (URTP), which lasts for about 10 s with a lifetime of 1.39 s, the first example to achieve the conversion of a fluorescence material to URTP by means of an external heating stimulus.
Journal ArticleDOI

Clusterization-triggered emission: Uncommon luminescence from common materials

TL;DR: In this paper, a comprehensive theory of the through-space conjugation (TSC) for these chromophores is proposed, and various applications have been envisioned, for example in the areas of process monitoring, structural visualization, sensors, and probes.
Journal ArticleDOI

Non-traditional intrinsic luminescence: inexplicable blue fluorescence observed for dendrimers, macromolecules and small molecular structures lacking traditional/conventional luminophores

TL;DR: Recently, a new photoluminescence phenomenon involving inexplicable blue fluorescence emissions was observed in simple aliphatic amines and poly(amidoamine) (PAMAM) dendrimers over two decades ago.
Journal ArticleDOI

The polymeric characteristics and photoluminescence mechanism in polymer carbon dots: A review

TL;DR: A large amount of emerging research on carbon dots (CDs) has been gradually improving the understanding of their structures, properties and emission mechanism as mentioned in this paper, and a new concept, polymer carbon dots, is put forward to generalize all kinds of CDs based on the summary of related reports.
References
More filters
Journal ArticleDOI

Luminescent metal–organic frameworks for chemical sensing and explosive detection

TL;DR: This review intends to provide an update of work published since then and focuses on the photoluminescence properties of MOFs and their possible utility in chemical and biological sensing and detection.
Journal ArticleDOI

Polymer sensors for nitroaromatic explosives detection

TL;DR: Several polymers have been used to detect nitroaromatic explosives by a variety of transduction schemes as mentioned in this paper, which relies on both electronic and structural interactions between the sensing material and the analyte.
Journal ArticleDOI

Economical, Green Synthesis of Fluorescent Carbon Nanoparticles and Their Use as Probes for Sensitive and Selective Detection of Mercury(II) Ions

TL;DR: A simple, economical, and green preparative strategy toward water-soluble, fluorescent carbon nanoparticles (CPs) with a quantum yield of approximately 6.9% by hydrothermal process using low cost wastes of pomelo peel as a carbon source for the first time is reported.
Journal ArticleDOI

Polyamine-Functionalized Carbon Quantum Dots as Fluorescent Probes for Selective and Sensitive Detection of Copper Ions

TL;DR: It is demonstrated that this facile methodology can offer a rapid, reliable, and selective detection of Cu(2+) with a detection limit as low as 6 nM and a dynamic range from 10 to 1100 nM.
Related Papers (5)