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Will Solar-Driven Water-Splitting Devices See the Light of Day?

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TLDR
In this paper, the major design constraints that motivate continued research in the field of solar-driven water splitting are summarized, and key device components that are now available for use in demonstration systems and prototypes.
Abstract
Through decades of sustained effort, researchers have made substantial progress on developing technologies for solar-driven water splitting. Nevertheless, more basic research is needed before prototype devices with a chance for commercial success can be demonstrated. In this Perspective, we summarize the major design constraints that motivate continued research in the field of solar-driven water splitting. Additionally, we discuss key device components that are now available for use in demonstration systems and prototypes. Finally, we highlight research areas where breakthroughs will be critical for continued progress toward commercial viability for solar-driven water-splitting devices.

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Citations
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Journal ArticleDOI

Engineering heterogeneous semiconductors for solar water splitting

TL;DR: In this paper, a critical review highlights some key factors influencing the efficiency of heterogeneous semiconductors for solar water splitting (i.e. improved charge separation and transfer, promoted optical absorption, optimized band gap position, lowered cost and toxicity, and enhanced stability and water splitting kinetics).
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Cobalt-iron (oxy)hydroxide oxygen evolution electrocatalysts: the role of structure and composition on activity, stability, and mechanism.

TL;DR: It is hypothesized that Fe is the most-active site in the catalyst, while CoOOH primarily provides a conductive, high-surface area, chemically stabilizing host.
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Research opportunities to advance solar energy utilization

TL;DR: Lewis reviews the status of solar thermal and solar fuels approaches for harnessing solar energy, as well as technology gaps for achieving cost-effective scalable deployment combined with storage technologies to provide reliable, dispatchable energy.
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Earth-Abundant Heterogeneous Water Oxidation Catalysts

TL;DR: It is suggested that future advances in solar fuels science will be accelerated by the development of new methods for materials synthesis and characterization, along with in-depth investigations of redox mechanisms at catalytic surfaces.
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High-Performance Electrocatalysis Using Metallic Cobalt Pyrite (CoS2) Micro- and Nanostructures

TL;DR: In this article, the authors report metallic cobalt pyrite (cobalt disulfide, CoS2) as one such high-activity candidate material and demonstrate that its specific morphology plays a crucial role in determining its overall catalytic efficacy.
References
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Journal ArticleDOI

Electrochemical Photolysis of Water at a Semiconductor Electrode

TL;DR: Water photolysis is investigated by exploiting the fact that water is transparent to visible light and cannot be decomposed directly, but only by radiation with wavelengths shorter than 190 nm.
Journal ArticleDOI

Solar Water Splitting Cells

TL;DR: The biggest challenge is whether or not the goals need to be met to fully utilize solar energy for the global energy demand can be met in a costeffective way on the terawatt scale.
Book

Atlas of Electrochemical Equilibria in Aqueous Solutions

TL;DR: The Atlas of Electrochemical Equilibria in Aqueous solutions as discussed by the authors is the most complete and complete work on aqueous solvents, which includes a detailed description of the properties of the solvers.
Journal ArticleDOI

Identification of active edge sites for electrochemical H2 evolution from MoS2 nanocatalysts.

TL;DR: The active site for hydrogen evolution, a reaction catalyzed by precious metals, on nanoparticulate molybdenum disulfide (MoS2) is determined by atomically resolving the surface of this catalyst before measuring electrochemical activity in solution.
Journal ArticleDOI

State of Understanding of Nafion

TL;DR: Light scattering experiments revealed that the radius of gyration had a linear dependence on the molar mass of the aggregates, which suggests that the particles are in the form of rods or ribbons, or at least some elongated structure.
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