B
Brian W. Skelton
Researcher at University of Western Australia
Publications - 1662
Citations - 33374
Brian W. Skelton is an academic researcher from University of Western Australia. The author has contributed to research in topics: Crystal structure & Ligand. The author has an hindex of 69, co-authored 1646 publications receiving 31889 citations. Previous affiliations of Brian W. Skelton include Monash University, Clayton campus & State University of Malang.
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Cluster chemistry: LXXV. Tetra-, penta- and hepta-nuclear clusters derived from {Ru4(μ-H)4(CO)11}2(μ-dppa) [dppa C2(PPh2)2]: X-ray structures of Ru4(μ-H)[μ3-HC2PPh2{Ru4(μ-H)4 (CO)11}](μ-PPh2)(μ-CO)(CO)9 and Ru7(μ-H)3(μ5-HC2PPh2)(μ-PPh2)(CO)16
TL;DR: In this article, the reaction between C2(PPh2)2 and Ru4(μ-H)4(CO)12 gave the Ru7 cluster, which on heating formed initially the hydrido-μ3-alkyne bis-Ru4 cluster Ru7(μ)-H)3(μ5-HC2PPh 2)(μ-PPh(2)-CO)16 (3), and the core in 3 has a new geometry, consisting of an Ru4 tetrahedron sharing an apical Ru atom with a C2Ru
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Proton Controlled Supramolecular Assembly: A Comparative Structural Study of Bis(2-guanidinobenzimidazolo)nickel(II) with Bis(2-guanidinobenzimidazole)nickel(II) Nitrate and 2-guanidinobenzimidazole
TL;DR: In this paper, it was shown that ligand deprotonation to yield bis(2-guanidinobenzimidazolo)nickel(II) restores much of the original hydrogen bonding capability of the uncomplexed ligand.
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Synthesis and structure of copper(I), silver(I) and zinc(II) amides [Cu2(mpsa)2, [Cu2X2 (mpsa)4] (X = Cl or Br), [Ag4 (mpsa)4] and [(ZnEt)2 (mpsa)2] [mpsa = 2-n (SiMe3)-C5H3N-6-Me]
Lutz M. Engelhardt,Geraldine E. Jacobsen,Wyona C. Patalinghug,Brian W. Skelton,Colin L. Raston,A. H. White +5 more
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Cobalt(II) and cobalt(III) complexes of a novel homoleptic thioether cage
TL;DR: In this paper, low-spin hexadentate cobalt(II) and cobalt-III complexes of the hexathioether cage (1,8-dimethyl-3,6,10,13,16,19-hexathiabicyclo[6.6]icosarie) have been synthesised, their redox and spectral properties have been investigated, and the encapsulation of the cobalt ion has been established by an X-ray crystal structure determination, which shows the metal ion to be coordinated to six thioether sulphur atoms at
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Stereochemistry and cycloaddition of 1,1,3-trioxy butadienes from β-keto esters
TL;DR: In this paper, the 1,1,3-trioxy dienes were characterized using spectroscopic analysis and characterisation of derived cycloadducts and crystallographic analysis of one of them.