B
Brian W. Skelton
Researcher at University of Western Australia
Publications - 1662
Citations - 33374
Brian W. Skelton is an academic researcher from University of Western Australia. The author has contributed to research in topics: Crystal structure & Ligand. The author has an hindex of 69, co-authored 1646 publications receiving 31889 citations. Previous affiliations of Brian W. Skelton include Monash University, Clayton campus & State University of Malang.
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Rearrangements of 1,3-diynes on ruthenium cluster carbonyls: isolation and structure of Ru6(PhCHC3C6H4)2(CO)15
TL;DR: In this article, the 1,3-diyne ligands are attached to two methyleneindyne molecules which are attached in η2 and η4 modes to a novel Ru6 cluster core.
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Cluster chemistry: LXXX. Reactions of Ru5(μ5-C2PPh2)(μ-PPh2)(CO)13 with 1,3-butadiene: addition to Cα and formation of a μ4-cyclohexenyne complex. X-Ray structures of Ru5{μ4-CC(PPh2)CH2-η3-CHCHCH2}(μ-PPh2)(μ-CO)(CO)11, Ru5{μ4-CC(PPh2)CHCH=CHMe}(μ-PPh2)(μ-CO)2(CO)9 and Ru5(μ4-C6H6)(μ-PPh2)2(CO)11
TL;DR: In this article, Ru 5 -{μ 4 -CC(PPh 2 )CH 2 -η 3 -CHCHCH 2 } (μ-PPh2 )(μ-CO)(CO) 11, (7, 8, 9, and 10) were characterised by single crystal X-ray studies.
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Reactions of Ru3(CO)10(NCMe)2 with ethyne: molecular structures of some prototypical cluster complexes
TL;DR: The synthesis of Ru4, Ru5 and Ru6 complexes accompanied by the synthesis of the previously described Ru3(µ3-C2H2)(µ-CO)(CO) was described in this paper.
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Solution stabilized monomeric dialkyl-aluminium and -gallium species, [MR2]. (R = 2-C(SiMe3)2C5H4N): from reduction of MR2Cl. Crystal structure of GaR2Cl
TL;DR: In this paper, an X-ray diffraction study of [GaR2Cl] has shown the metal to be in a distorted trigonal bipyramidal environment with apical N-centres.
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Energy transfer between Eu3+ and Nd3+ in near-infrared emitting β-triketonate coordination polymers.
Laura Abad Galán,Laura Abad Galán,Alexandre N. Sobolev,Brian W. Skelton,Eli Zysman-Colman,Mark I. Ogden,Massimiliano Massi +6 more
TL;DR: Isomorphous β-triketonate-based lanthanoid polymers containing tris(4-methylbenzoyl)methanide and Rb+ with formula {[Ln(Rb)(mtbm)4]2}n (Ln = Eu3+ and Nd3+) have been synthesised and structurally characterised.