B
Brian W. Skelton
Researcher at University of Western Australia
Publications - 1662
Citations - 33374
Brian W. Skelton is an academic researcher from University of Western Australia. The author has contributed to research in topics: Crystal structure & Ligand. The author has an hindex of 69, co-authored 1646 publications receiving 31889 citations. Previous affiliations of Brian W. Skelton include Monash University, Clayton campus & State University of Malang.
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A novel heterometallic μ4-oxo-bridged complex based on an octahedral Cd2Cu4 skeleton via the reaction of elemental copper, cadmium acetate and amino alcohol
TL;DR: In this paper, the reaction of copper powder in dmso with cadmium acetate hydrate and 2-dimethylaminoethanol (HL), in open air, is shown.
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Complexes of (phenazine)–˙ and (phenazine)2– with magnesium(II): syntheses of [Mg(C12H8N2)2(thf)3], [Mg(C12H8N2)(thf)2], and [Mg2Br2(C12H8N2)(thf)6]·[MgBr2(thf)4](thf = tetrahydrofuran)(X-ray authenticated)
TL;DR: Phenazine and magnesium in tetrahydrofuran at ca. 20 °C afforded a paramagnetic complex, [Mg(C12H8N2)2(thf)3] as discussed by the authors.
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Reactions of Ru5(μ5-C2)(μ-SMe)2(μ-PPh2)2(CO)11 with C2(SiMe3)2: formation of butatrienylidene complexes and related chemistry. X-ray crystal structures of Ru5{μ5-CC[C2(SiMe3)]C(SiMe3)C(SiMe3)}(μ3-SMe)(μ-PPh2)2(CO)10, Ru5(μ5-CCCCH2)(μ3-SMe)(μ-SMe)(μ-PPh2)2(CO)10 and Ru5(μ5-CCCCH2)(μ-SMe)2(μ-PPh2)2(CO)11
TL;DR: In this article, the dicarbon-containing complex Ru5(μ5-C2)(μ-SMe)2 (μ-PPh2)2(CO)11 (1) and C2(SiMe3)2 afforded two isomers of Ru5{m5-CCCCH(SiME3)}(μ3-Sme)(mSMe)(mMe),mMe,mS,mMe) 2(μ-pPh2,mPPh 2(CO),2(1),2(2)
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The addition of small molecules to (η-C5H5)2Rh2(CO)(CF3C2CF3)—IX. CH bond activation in the reactions with dienes, polyenes and arenes; the crystal and molecular structure of [(η-C5H5)2Rh2{C(CF3)C(CF3)H}]2(C6H4)
TL;DR: In this paper, the structure of (η-C5H5)2Rh2{C(CF3C2CF3)H]2 (C6H4) was derived from the reaction with benzene, which was confirmed by single crystal X-ray diffraction studies.
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Synthesis and Structures of Homoleptic Monomeric Potassium Aryloxolanthanoidate(III) Complexes
TL;DR: In this article, the reaction of tris(2, 6-diphenylphenolates) [Ln(Odpp)3] with KOdpp in 1, 2, 4, 5-tetramethylbenzene (durene) at 200-250 °C has been obtained.