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Brian W. Skelton
Researcher at University of Western Australia
Publications - 1662
Citations - 33374
Brian W. Skelton is an academic researcher from University of Western Australia. The author has contributed to research in topics: Crystal structure & Ligand. The author has an hindex of 69, co-authored 1646 publications receiving 31889 citations. Previous affiliations of Brian W. Skelton include Monash University, Clayton campus & State University of Malang.
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Hydrogen-bonding ‘Pd(OH)…2(HOAr)’ and ‘[Pd(OH2)+…−OArl2’, and protonation of a hydroxo-ligand by pentafluorophenol in organopalladium(IV) chemistry. Structural studies of the pallada(IV) cyclopentane adducts [Pd(OH)(C4H8){(pz)3BH}.2(3-MeC6H4OH)] and [Pd(OH2)(C4H8){(pz)3BH}.(C6F5O)]2 [(pz)3BH = tris(pyrazol-1-yl)borate]
TL;DR: The first structural studies in diorganopalladium(IV) chemistry include the firs examples of hydroxo-and aqua-palladium (IV) complexes, and also models for possible pallada-cyclic intermediates in organic synthesis involving palladium complexes as catalysts.
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Facile Metal-Directed Synthesis and Crystal Structure of a New Amino Acid Ester, Methyl 3-[(2-Aminoethyl)amino]-2-[(2-aminoethyl)aminomethyl]propionate, as the Copper(II) Complex
TL;DR: In this paper, the copper ion lies in a near plane of four nitrogens with perchlorates occupying axial sites, and the new amino acid ester complex (ethyl hydrogen bis [(2-aminoethyl ) aminomethyl ] malonate )copper(II) perchlorate, [Cu(1)] (ClO4)2.
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One-pot Annulation of Enones with Lithiated Allyl Phenyl Sulfone
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Conformationally flexible p-Sulfonated Calix[5]arene binding with large Bis-Phosphonium cations
TL;DR: Water-soluble p-sulfonated calix(5)arenes are significantly distorted from the common cone conformation and are linked from one bilayer to another through the sulfonate groups via secondary coordination sphere interactions associated with homoleptic aquated metal ions.
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Tetraazacycloalkanes With Pendant Carboxylates. Copper(II)-Directed Syntheses and Crystal Structure of (Ethyl 1,5,9,13-tetraazabicyclo[11.2.2]heptadecane-7-carboxylate)copper(II) Perchlorate
TL;DR: In this article, the reaction of copper(II) complexes of the tetraamines H2N-(CH2)n-NH-(CH 2)m-NH-CH2-NH2 (n, m=5, 6), N,N′- bis (3-aminopropyl)-1,4-diazacyclohexane and ethane-1,2-diamine with formaldehyde and diethyl malonate in methanolic base produces macrocycles where initially new -NH- CH2-C( C