B
Brian W. Skelton
Researcher at University of Western Australia
Publications - 1662
Citations - 33374
Brian W. Skelton is an academic researcher from University of Western Australia. The author has contributed to research in topics: Crystal structure & Ligand. The author has an hindex of 69, co-authored 1646 publications receiving 31889 citations. Previous affiliations of Brian W. Skelton include Monash University, Clayton campus & State University of Malang.
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Coordinating Tectons 4: Coordination Chemistry of the 4,5-Diazafluoren-9-yl Moiety as a Metallo-Ligand for Allenylidene Complexes
TL;DR: In this article, the 4,5-diazafluoren-9-yl moiety has been utilized in the construction of multinuclear complexes incorporating a ruthenium(II) allenylidene functionality.
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Alkene analogues of bis(N-donor)ketone ligands: ruthenium(II) complexes containing 1-(pyridin-2-yl)-1-(N-methylimidazol-2-yl)ethene and 1,1-bis(N-methylimidazol-2-yl)ethene ((mim)2CCH2), and structural studies of [Ru(bpy)2{(mim)2CCH2}][PF6]2 (bpy=2,2′-bipyridine) and the pyridine-2-carboxylate (pyCO2 −) complex [Ru(bpy)2(pyCO2)][PF6]
TL;DR: In this paper, the pyridine-2-carboxylate complex [Ru(bpy)2(pyCO2)][PF6] has been shown to have distorted octahedral geometry for ruthenium(II).
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The Synthesis, Structures and Polymorphism of the Dimeric Trivalent Rare-Earth 3,5-Dimethylpyrazolate Complexes [Ln(Me2pz)3(thf)]2
Glen B. Deacon,Glen B. Deacon,Rita Harika,Peter C. Junk,Brian W. Skelton,Daniel Werner,Allan H. White +6 more
TL;DR: A variety of rare-earth 3,5-dimethyl pyrazolate (Me2pz) complexes have been synthesized by direct reaction of Hg-activated metal with Me2pZH as a pro-ligand at elevated temperatures, by redox transmetalation/protolysis with the lanthanoid element, Hg(C6F5)2, and Me 2pzH, and by protolysis of tris[bis(trimethylsilyl)amido]cerium(III) with Me 2
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Crystal structures of 2-Hydroxyimino-1-phenylethan-1-one and ethyl 3-Oxo-2-sodiooxyiminobutanoate
TL;DR: The crystal structures of the title compounds, PhCOCH=NOH (5) and Na+[MeCOC(=NO-)CO2Et],-2H2O (10), have been determined by single-crystal X-ray diffraction at 295 K and refined by least squares to R 0.051, 0.062 (815, 1199 'observed' reflections) respectively.
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Cluster chemistry: LXXVII. Carbide clusters from Ru5(μ5-C2PPh2)-(μ-PPh2)(CO)13 and Fe2(CO)9: X-ray structures of MRu4(μ5-C)(μ-dppm)(CO)13 · 0.5CH2Cl2 (M = Fe and Ru) and FeRu5(μ-6-C)(μ-PPh2)2(CO)13(PMe2Ph)
TL;DR: In this paper, five complexes have been isolated from the reaction between Ru 5 (μ 5 -C 2 PPh 2 )(μ-PPh2 )(CO) 13 ( 1 ) and Fe 2 (CO) 9, including the previously described isomer of ( 1), Ru 5(μ 5-C 2 Ph)(μ 4 -PPh)(μ-pPh 2 ))(CO), and the dicarbido complex Fe 3 Ru 5