B
Brian W. Skelton
Researcher at University of Western Australia
Publications - 1662
Citations - 33374
Brian W. Skelton is an academic researcher from University of Western Australia. The author has contributed to research in topics: Crystal structure & Ligand. The author has an hindex of 69, co-authored 1646 publications receiving 31889 citations. Previous affiliations of Brian W. Skelton include Monash University, Clayton campus & State University of Malang.
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Diastereoselective reductions of β-substituted-γ-keto sulfoximines and a novel palladium(0)-catalysed allylic sulfoximine to allylic sulfinamide rearrangement
TL;DR: The reduction of β-substituted-γ-keto N-tosyl Sulfoximines is highly diastereoselective and the allies products undergo a facile rearrangement to allylic sulfinamides in the presence of a palladium(0) catalyst.
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Access to 1,2,3,4-Tetraoxygenated Benzenes via a Double Baeyer–Villiger Reaction of Quinizarin Dimethyl Ether: Application to the Synthesis of Bioactive Natural Products from Antrodia camphorata
Harriet L. Newson,Duncan A. Wild,Sing Yee Yeung,Brian W. Skelton,Gavin R. Flematti,Jane E. Allan,Matthew J. Piggott +6 more
TL;DR: The first systematic investigation into the Baeyer-Villiger reaction of an anthraquinone is presented, and the axially chiral biphenyl was found to be configurationally stable, but the resolved enantiomers exhibit no optical activity at the αD-line.
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Synthetic, Structural and Vibrational Spectroscopic Studies in Bismuth(III) Halide/N,N′-Aromatic Bidentate Base Systems. II Bipyridinium (2,2' Bipyridine) tetraholobismuthate (III) (Halogen = Chloride or Bromide)
TL;DR: In this article, synthesis and room-temperature single-crystal X-ray structure determinations are recorded for the title compounds, [bpyH]+[(bpy)BiX4]-, X = Cl, Br, the chloride being obtained in a second acetonitrile-sesquisolvated form.
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Self-assembly directed by NH⋅⋅⋅O hydrogen bonding: New layered molecular arrays derived from 4-tert- butylbenzoic acid and aliphatic diamines
Robert S. Armstrong,Ian Atkinson,Elizabeth A. Carter,Myrna S. Mahinay,Brian W. Skelton,Peter A. Turner,Gang Wei,Allan H. White,Leonard F. Lindoy +8 more
TL;DR: The adoption of new three-dimensional molecular arrays through cocrystallization of the above diamines and 4-tert-butylbenzoic acid seems to reflect a tendency toward maximization of both the number and strengths of the hydrogen bond interactions in the respective ionic layers.
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Spectroscopic and structural studies on adducts of silver(I) cyanide with ER3 ligands (E = P, As or Sb)
Graham A. BowmakerEffendy,Jason C. Reid,Clifton E. F. Rickard,Brian W. Skelton,Allan H. White +4 more
TL;DR: In this paper, the properties of the adducts AgCN∶EPh3 (E = P, As or Sb) (1∶2) and AgCN ∶PPh3(1∵1) have been characterized by room temperature single crystal structure determination and low frequency vibrational spectroscopy.