H
Hiroshi Nishihara
Researcher at Keio University
Publications - 677
Citations - 17201
Hiroshi Nishihara is an academic researcher from Keio University. The author has contributed to research in topics: Medicine & Terpyridine. The author has an hindex of 62, co-authored 616 publications receiving 14683 citations. Previous affiliations of Hiroshi Nishihara include Tokyo University of Science & Ochanomizu University.
Papers
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Normal and inverted redox potentials and structural changes tuned by medium effects in [M2Mo(η5-C5Me5)2(S2C6H4)2(CO)2] (M: Co, Rh)
Satoshi Muratsugu,Satoshi Muratsugu,Keitaro Sodeyama,Keitaro Sodeyama,Fusao Kitamura,Satoru Tsukada,Mizuki Tada,Shinji Tsuneyuki,Hiroshi Nishihara +8 more
TL;DR: In this paper, the two-electron (2e−) reduction of two novel heterometal trinuclear complexes, [Co2Mo(η5-C5Me5)2(S2C6H4)2
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Control of coordination and luminescence properties of lanthanide complexes using octadentate oligopyridine-amine ligands
Atsushi Wada,Masayuki Watanabe,Masayuki Watanabe,Yoshinori Yamanoi,Takuya Nankawa,Kosuke Namiki,Mikio Yamasaki,Masaki Murata,Hiroshi Nishihara +8 more
TL;DR: In this paper, Lanthanide complexes with linear and cyclic octadentate oligopyridine-amine ligands were synthesized, and their molecular structures were determined by single-crystal X-ray crystallography.
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Synthesis of a vinylene-bridged ferrocene-hydroquinone complex and its unusual structural change originated by proton-coupled electron transfer.
TL;DR: The vinylene-bridged ferrocene−hydroquinone complex, 1, underwent 2-electron oxidation and 2-proton elimination by a redox reaction with 1,1‘-dichloroferrocenium hexafluorophosphate as a 1-electrons oxidizing agent in methanol to form 3, which includes a novel allene and a quinonoid structure.
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Synthesis of pendant-type anthraquinone-bridged cofacial dinuclear platinum(II) complexes and their emission properties.
TL;DR: It is postulated that the restriction of the Pt-Pt distance flexibility in the rigid structure of 3 prevents the significant increase of the pt-PT interaction at the excited state.
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Redox Properties of Hepta(1,1′-dihexylferrocenylene)
TL;DR: In this article, a heptamer was isolated using recycling GPC cyclic voltammetry and square-wave voltammetric data and the distribution of formal potentials can be explained using interaction parameters over two and three redox units.