H
Hiroshi Nishihara
Researcher at Keio University
Publications - 677
Citations - 17201
Hiroshi Nishihara is an academic researcher from Keio University. The author has contributed to research in topics: Medicine & Terpyridine. The author has an hindex of 62, co-authored 616 publications receiving 14683 citations. Previous affiliations of Hiroshi Nishihara include Tokyo University of Science & Ochanomizu University.
Papers
More filters
Journal ArticleDOI
Metal complex oligomer and polymer wires on electrodes: Tactical constructions and versatile functionalities
TL;DR: In this paper, a review of recent progress in the construction of metal complex wires on various substrates via the stepwise coordination method, their functions, and the electrochemical evaluation of bis(terpyridine)metal complex oligomer wires on electrodes is presented.
Journal ArticleDOI
Synthesis of heterometal cluster complexes by the reaction of cobaltadichalcogenolato complexes with groups 6 and 8 metal carbonyls.
Masaki Murata,Satoru Habe,Shingo Araki,Kosuke Namiki,Teppei Yamada,Norikiyo Nakagawa,Takuya Nankawa,Masayuki Nihei,Jun Mizutani,Masato Kurihara,Hiroshi Nishihara +10 more
TL;DR: In the dinuclear group 8 metal-Co complexes, 5 and 6, the CpCo(S2C6H4) moiety and the metal carbonyl moiety act as a Lewis acid character and a base character, respectively, as determined by their spectrochemical and redox properties.
Journal ArticleDOI
Synthesis, redox behavior and electrodeposition of biferrocene-modified gold clusters ☆
TL;DR: In this paper, a 2.2 ± 0.3 nm-diameter Au core with 20 biferrocene-terminated thiolates and 75 octyl thiolate on average was synthesized.
Journal ArticleDOI
Electron transport dynamics in redox-molecule-terminated branched oligomer wires on Au(111).
Ryota Sakamoto,Shunsuke Katagiri,Hiroaki Maeda,Yoshihiko Nishimori,Seiji Miyashita,Hiroshi Nishihara +5 more
TL;DR: A simple electron transport mechanism based on intrawire electron hopping between two adjacent redox-active sites is proposed, and the numerical simulation thereof reproduced the series of "asymmetric" potential-step chronoamperometry results for both linear and branched bis(terpyridine)iron(II) wires.
Journal ArticleDOI
Visible-light photochromism of triarylamine- or ferrocene-bound diethynylethenes that switches electronic communication between redox sites and luminescence.
TL;DR: Redox-active ferrocene- and triarylamine-terminated diethynylethene derivatives have been synthesized and their photochromic properties and switching behavior based on through-bond electronic communication between the two redox sites, as well as their emissions, have been examined.