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Showing papers by "North Carolina State University published in 2004"


Journal ArticleDOI
TL;DR: In this article, the authors focused on temperature and pH responsive polymer systems and additionally the other stimuli-based responsive polymers will be assessed, which is more helpful to design new approaches because the basic concepts and mechanisms are systematically connected.

2,233 citations


Journal ArticleDOI
01 Mar 2004-Ecology
TL;DR: A complete new conceptual model of the soil N cycle needs to incorporate recent research on plant–microbe competition and microsite processes to explain the dynamics of N across the wide range of N availability found in terrestrial ecosystems.
Abstract: Until recently, the common view of the terrestrial nitrogen cycle had been driven by two core assumptions—plants use only inorganic N and they compete poorly against soil microbes for N. Thus, plants were thought to use N that microbes “left over,” allowing the N cycle to be divided cleanly into two pieces—the microbial decomposition side and the plant uptake and use side. These were linked by the process of net mineralization. Over the last decade, research has changed these views. N cycling is now seen as being driven by the depolymerization of N-containing polymers by microbial (including mycorrhizal) extracellular enzymes. This releases organic N-containing monomers that may be used by either plants or microbes. However, a complete new conceptual model of the soil N cycle needs to incorporate recent research on plant–microbe competition and microsite processes to explain the dynamics of N across the wide range of N availability found in terrestrial ecosystems. We discuss the evolution of thinking abou...

2,126 citations


Journal ArticleDOI
TL;DR: In this article, the authors examine the various links among foreign direct investment (FDI), financial markets, and economic growth, and explore whether countries with better financial systems can exploit FDI more efficiently.

1,747 citations


Journal ArticleDOI
TL;DR: The propensity score, the probability of treatment exposure conditional on covariates, is the basis for two approaches to adjusting for confounding: methods based on stratification of observations by quantiles of estimated propensity scores and methods based upon weighting observations by the inverse of estimated covariates.
Abstract: Estimation of treatment effects with causal interpretation from observational data is complicated because exposure to treatment may be confounded with subject characteristics. The propensity score, the probability of treatment exposure conditional on covariates, is the basis for two approaches to adjusting for confounding: methods based on stratification of observations by quantiles of estimated propensity scores and methods based on weighting observations by the inverse of estimated propensity scores. We review popular versions of these approaches and related methods offering improved precision, describe theoretical properties and highlight their implications for practice, and present extensive comparisons of performance that provide guidance for practical use.

1,548 citations


Journal ArticleDOI
TL;DR: This poster presents a selection of photographs from around the world taken in the period of May 21 to 29, 1997, as well as some of the more recent photographs taken in China and the United States.
Abstract: Pieter Baas – Leiden, The Netherlands Nadezhda Blokhina – Vladivostok, Russia Tomoyuki Fujii – Ibaraki, Japan Peter Gasson – Kew, UK Dietger Grosser – Munich, Germany Immo Heinz – Munich, Germany Jugo Ilic – South Clayton, Australia Jiang Xiaomei – Beijing, China Regis Miller – Madison, WI, USA Lee Ann Newsom – University Park, PA, USA Shuichi Noshiro – Ibaraki, Japan Hans Georg Richter – Hamburg, Germany Mitsuo Suzuki – Sendai, Japan Teresa Terrazas – Montecillo, Mexico Elisabeth Wheeler – Raleigh, NC, USA Alex Wiedenhoeft – Madison, WI, USA

1,308 citations



Journal ArticleDOI
TL;DR: The process of oxidative stress and the pathways by which it relates to many chronic diseases are examined and the role that endogenous and exogenous antioxidants may play in controlling oxidation and the evidence of their roles in preventing disease is reviewed.
Abstract: The generation of reactive oxygen species (ROS) and other free radicals (R) during metabolism is a necessary and normal process that ideally is compensated for by an elaborate endogenous antioxidant system. However, due to many environmental, lifestyle, and pathological situations, excess radicals can accumulate, resulting in oxidative stress. Oxidative stress has been related to cardiovascular disease, cancer, and other chronic diseases that account for a major portion of deaths today. Antioxidants are compounds that hinder the oxidative processes and thereby delay or prevent oxidative stress. This article examines the process of oxidative stress and the pathways by which it relates to many chronic diseases. We also discuss the role that endogenous and exogenous antioxidants may play in controlling oxidation and review the evidence of their roles in preventing disease.

1,093 citations


Journal ArticleDOI
TL;DR: Jasmine asserted that racism is prevalent in students at Wells Academy, an elite, pre-ership activities and was an athlete as discussed by the authors and was also very active in school leadership thatWells Academy is located in a major city activities.
Abstract: J asmine,' an African-American 9thexamining the educational experiences of cluding areas that can be considered upper grade student, described the racial and African-American students. Critical Race class, middle class, and less affluent areas. cultural climate at Wells Academy, an Theory (CRT) is a useful perspective from Most of the African American students, elite, predominately White, independent which to explore such phenomena. In this however, are considered middle class.2 school. She stated, "Everybody knows that article, we will illustrate how CRT can be Two such African-American students racism exists and that people are racist. So used to examine the experiences of were Malcolm and Barbara. Malcolm was when it comes out, they [faculty and stuAfrican-American students. We will use a 17-year-old senior from a middle-class dents] aren't that surprised that it is there." the counterstories of African-American family. He was very active in school leadAs Jasmine asserted, racism is prevalent in students at Wells Academy, an elite, preership activities and was an athlete. Barall aspects of society, with schools not dominately White, independent school. bara was an 18-year-old recent graduate being an exception. However, what is Wells Academy from a prominent, upper-class family. She most interesting about her statement is was also very active in school leadership thatWells Academy is located in a major city activities. Both students were very proud monplace within the school walls that in an affluent, predominately White area of their African-American heritage and monplace within the school walls that in the southeastern United States. Propoften participated in the African-Ameriwhen it appears, e erty values in this community range from can cultural activities at Wells. has already begun to understand the per$450,000 to over $3 million. Wells has Because of Malcolm's and Barbara's

1,014 citations


Proceedings ArticleDOI
07 Mar 2004
TL;DR: This work presents a new congestion control scheme that alleviates RTT unfairness while supporting TCP friendliness and bandwidth scalability, and uses two window size control policies called additive increase and binary search increase.
Abstract: High-speed networks with large delays present a unique environment where TCP may have a problem utilizing the full bandwidth. Several congestion control proposals have been suggested to remedy this problem. The existing protocols consider mainly two properties: TCP friendliness and bandwidth scalability. That is, a protocol should not take away too much bandwidth from standard TCP flows while utilizing the full bandwidth of high-speed networks. This work presents another important constraint, namely, RTT (round trip time) unfairness where competing flows with different RTTs may consume vastly unfair bandwidth shares. Existing schemes have a severe RTT unfairness problem because the congestion window increase rate gets larger as the window grows ironically the very reason that makes them more scalable. RTT unfairness for high-speed networks occurs distinctly with drop tail routers for flows with large congestion windows where packet loss can be highly synchronized. After identifying the RTT unfairness problem of existing protocols, This work presents a new congestion control scheme that alleviates RTT unfairness while supporting TCP friendliness and bandwidth scalability. The proposed congestion control algorithm uses two window size control policies called additive increase and binary search increase. When the congestion window is large, additive increase with a large increment ensures square RTT unfairness as well as good scalability. Under small congestion windows, binary search increase supports TCP friendliness. The simulation results confirm these properties of the protocol.

984 citations


Journal ArticleDOI
TL;DR: A comprehensive survey of all issues associated with PageRank, covering the basic PageRank model, available and recommended solution methods, storage issues, existence, uniqueness, and convergence properties, possible alterations to the basic model, and suggested alternatives to the traditional solution methods.
Abstract: This paper serves as a companion or extension to the "Inside PageRank" paper by Bianchini et al. [Bianchini et al. 03]. It is a comprehensive survey of all issues associated with PageRank, covering the basic PageRank model, available and recommended solution methods, storage issues, existence, uniqueness, and convergence properties, possible alterations to the basic model, suggested alternatives to the traditional solution methods, sensitivity and conditioning, and finally the updating problem. We introduce a few new results, provide an extensive reference list, and speculate about exciting areas of future research.

910 citations


Journal ArticleDOI
TL;DR: The goal of this paper is to summarize the various potential causes of extreme scores in a data set, how to detect them, and whether they should be removed or not, and how significantly a small proportion of outliers can affect even simple analyses.
Abstract: There has been much debate in the literature regarding what to do with extreme or influential data points. The goal of this paper is to summarize the various potential causes of extreme scores in a data set (e.g., data recording or entry errors, motivated mis-reporting, sampling errors, and legitimate sampling), how to detect them, and whether they should be removed or not. Another goal of this paper was to explore how significantly a small proportion of outliers can affect even simple analyses. The examples show a strong beneficial effect of removal of extreme scores. Accuracy tended to increase significantly and substantially, and errors of inference tended to drop significantly and substantially once extreme scores were removed. The presence of outliers can lead to inflated error rates and substantial distortions of parameter and statistic estimates when using either parametric or nonparametric tests (e.g., Zimmerman, 1994, 1995, 1998). Casual observation of the literature suggests that researchers rarely report checking for outliers of any sort. This inference is supported empirically by Osborne, Christiansen, and Gunter (2001), who found that authors reported testing assumptions of the statistical procedure(s) used in their studies--including checking for the presence of outliers--only 8% of the time. Given what we know of the importance of assumptions to accuracy of estimates and error rates, this in itself is alarming. There is no reason to believe that the situation is different in other social science disciplines. What are Outliers and Fringeliers and why do we care about them?

Journal ArticleDOI
TL;DR: In this paper, the relationship between social capital and knowledge creation at the individual level was analyzed, and a limited theory of knowledge creation was proposed, which encompasses the number and strength of the relat...
Abstract: This study analyzed the relationship between social capital and knowledge creation at the individual level. Our limited theory of knowledge creation encompasses the number and strength of the relat...

Journal ArticleDOI
TL;DR: In this article, a review suggests that this technology has immense potential for research in basic and applied animal ecology and that efforts to incorporate biotelemetry into broader ecological research programs should yield novel information that has been challenging to collect historically from free-ranging animals in their natural environments.
Abstract: Remote measurement of the physiology, behaviour and energetic status of free-living animals is made possible by a variety of techniques that we refer to collectively as 'biotelemetry'. This set of tools ranges from transmitters that send their signals to receivers up to a few kilometers away to those that send data to orbiting satellites and, more frequently, to devices that log data. They enable researchers to document, for long uninterrupted periods, how undisturbed organisms interact with each other and their environment in real time. In spite of advances enabling the monitoring of many physiological and behavioural variables across a range of taxa of various sizes, these devices have yet to be embraced widely by the ecological community. Our review suggests that this technology has immense potential for research in basic and applied animal ecology. Efforts to incorporate biotelemetry into broader ecological research programs should yield novel information that has been challenging to collect historically from free-ranging animals in their natural environments. Examples of research that would benefit from biotelemetry include the assessment of animal responses to different anthropogenic perturbations and the development of life-time energy budgets.

Journal ArticleDOI
TL;DR: Aflatoxins, a group of polyketide-derived furanocoumarins, are the most toxic and carcinogenic compounds among the known mycotoxins and there are only four major aflatoxINS, B1, B2, G1, and G2.
Abstract: Aflatoxins, a group of polyketide-derived furanocoumarins (Fig. [1][1]), are the most toxic and carcinogenic compounds among the known mycotoxins. Among the at least 16 structurally related aflatoxins characterized, however, there are only four major aflatoxins, B1, B2, G1, and G2 (AFB1, AFG1, AFB2

Journal ArticleDOI
TL;DR: Evidence is found that the most global model considered provides a poor fit to the data, hence an overdispersion factor is estimated to adjust model selection procedures and inflate standard errors.
Abstract: Few species are likely to be so evident that they will always be detected at a site when present. Recently a model has been developed that enables estimation of the proportion of area occupied, when the target species is not detected with certainty. Here we apply this modeling approach to data collected on terrestrial salamanders in the Plethodon glutinosus complex in the Great Smoky Mountains National Park, USA, and wish to address the question “how accurately does the fitted model represent the data?” The goodness-of-fit of the model needs to be assessed in order to make accurate inferences. This article presents a method where a simple Pearson chi-square statistic is calculated and a parametric bootstrap procedure is used to determine whether the observed statistic is unusually large. We found evidence that the most global model considered provides a poor fit to the data, hence estimated an overdispersion factor to adjust model selection procedures and inflate standard errors. Two hypothetical datasets with known assumption violations are also analyzed, illustrating that the method may be used to guide researchers to making appropriate inferences. The results of a simulation study are presented to provide a broader view of the methods properties.

Journal ArticleDOI
TL;DR: In this paper, the authors extended previous research on two approaches to human-centred automation: intermediate levels of automation (LOAs) for maintaining operator involvement in complex systems control and facilitating situation awareness; and adaptive automation (AA) for managing operator workload through dynamic control allocations between the human and machine over time.
Abstract: This paper extends previous research on two approaches to human-centred automation: (1) intermediate levels of automation (LOAs) for maintaining operator involvement in complex systems control and facilitating situation awareness; and (2) adaptive automation (AA) for managing operator workload through dynamic control allocations between the human and machine over time. Some empirical research has been conducted to examine LOA and AA independently, with the objective of detailing a theory of human-centred automation. Unfortunately, no previous work has studied the interaction of these two approaches, nor has any research attempted to systematically determine which LOAs should be used in adaptive systems and how certain types of dynamic function allocations should be scheduled over time. The present research briefly reviews the theory of human-centred automation and LOA and AA approaches. Building on this background, an initial study was presented that attempts to address the conjuncture of these two approa...

Journal ArticleDOI
TL;DR: In this article, the authors of four disciplines at varying stages of adoption of open access were examined to see whether they have a greater impact as measured by citations in the ISI Web of Science database when their authors make them freely available on the Internet.
Abstract: Although many authors believe that their work has a greater research impact if it is freely available, studies to demonstrate that impact are few. This study looks at articles in four disciplines at varying stages of adoption of open access—philosophy, political science, electrical and electronic engineering and mathematics—to see whether they have a greater impact as measured by citations in the ISI Web of Science database when their authors make them freely available on the Internet. The finding is that, across all four disciplines, freely available articles do have a greater research impact. Shedding light on this category of open access reveals that scholars in diverse disciplines are adopting open-access practices and being rewarded for it.

Journal ArticleDOI
TL;DR: A review of the evidence on the properties of the nuclei A = 8, 9 and 10, with emphasis on material leading to information about the structure of the A =8, 9, 10 systems is given in this paper.

Journal ArticleDOI
TL;DR: In this article, the contact honey bee toxicity of commercial and candidate neonicotinoid insecticides was evaluated and it was shown that P450s are an important mechanism for acetamiprid and thiacloprid detoxification and their low toxicity to honey bees.

Proceedings ArticleDOI
09 May 2004
TL;DR: This paper presents an interleaved hop-by-hop authentication scheme that guarantees that the base station will detect any injected false data packets when no more than a certain number t nodes are compromised.
Abstract: Sensor networks are often deployed in unattended environments, thus leaving these networks vulnerable to false data injection attacks in which an adversary injects false data into the network with the goal of deceiving the base station or depleting the resources of the relaying nodes. Standard authentication mechanisms cannot prevent this attack if the adversary has compromised one or a small number of sensor nodes. In this paper, we present an interleaved hop-by-hop authentication scheme that guarantees that the base station will detect any injected false data packets when no more than a certain number t nodes are compromised. Further, our scheme provides an upper bound B for the number of hops that a false data packet could be forwarded before it is detected and dropped, given that there are up to t colluding compromised nodes. We show that in the worst case B is O(t/sup 2/). Through performance analysis, we show that our scheme is efficient with respect to the security it provides, and it also allows a tradeoff between security and performance.

Journal ArticleDOI
TL;DR: This article addresses dynamic service selection via an agent framework coupled with a QoS ontology with the aim of enabling participants to collaborate to determine each other's service quality and trustworthiness.
Abstract: Current Web services standards lack the means for expressing a service's nonfunctional attributes - namely, its quality of service. QoS can be objective (encompassing reliability, availability, and request-to-response time) or subjective (focusing on user experience). QoS attributes are key to dynamically selecting the services that best meet user needs. This article addresses dynamic service selection via an agent framework coupled with a QoS ontology. With this approach, participants can collaborate to determine each other's service quality and trustworthiness.

Journal ArticleDOI
TL;DR: It is suggested that parents continue to exert an influential role in late adolescent drinking behavior, such that higher levels of perceived parental involvement were associated with weaker relations between peer influences and alcohol use and problems.
Abstract: This study investigated the influences of peer and parent variables on alcohol use and problems in a sample of late adolescents in the summer immediately prior to entry into college. Participants (N = 556) completed a mail survey assessing peer influences (alcohol offers, social modeling, perceived norms), parental behaviors (nurturance, monitoring), and attitudes and values (disapproval for heavy drinking, permissiveness for drinking), and alcohol use and alcohol-related consequences. Hierarchical regression analyses indicated significant associations between both peer and parental influences and alcohol involvement, and showed that parental influences moderated peer-influence-drinking behavior, such that higher levels of perceived parental involvement were associated with weaker relations between peer influences and alcohol use and problems. These findings suggest that parents continue to exert an influential role in late adolescent drinking behavior.

Journal ArticleDOI
TL;DR: The fiber-reactive chitosan derivative, O-acrylamidomethyl- HTCC (NMA-HTCC), showed complete bacterial reduction within 20 min at the concentration of 10ppm, when contacted with Staphylococcus aureus and Escherichia coli.

Journal ArticleDOI
TL;DR: In this article, high-resolution seismic profiles from the North Yellow Sea reveal a 20-40m-thick subaqueous clinoform delta that wraps around the eastern end of the Shandong Peninsula, extending into the South Yellow Sea.

Proceedings ArticleDOI
29 Sep 2004
TL;DR: It is found that optimizing fairness usually increases throughput, while maximizing throughput does not necessarily improve fairness, and two algorithms are proposed that optimize fairness.
Abstract: This paper presents a detailed study of fairness in cache sharing between threads in a chip multiprocessor (CMP) architecture. Prior work in CMP architectures has only studied throughput optimization techniques for a shared cache. The issue of fairness in cache sharing, and its relation to throughput, has not been studied. Fairness is a critical issue because the operating system (OS) thread scheduler's effectiveness depends on the hardware to provide fair cache sharing to co-scheduled threads. Without such hardware, serious problems, such as thread starvation and priority inversion, can arise and render the OS scheduler ineffective. This paper makes several contributions. First, it proposes and evaluates five cache fairness metrics that measure the degree of fairness in cache sharing, and shows that two of them correlate very strongly with the execution-time fairness. Execution-time fairness is defined as how uniform the execution times of co-scheduled threads are changed, where each change is relative to the execution time of the same thread running alone. Secondly, using the metrics, the paper proposes static and dynamic L2 cache partitioning algorithms that optimize fairness. The dynamic partitioning algorithm is easy to implement, requires little or no profiling, has low overhead, and does not restrict the cache replacement algorithm to LRU. The static algorithm, although requiring the cache to maintain LRU stack information, can help the OS thread scheduler to avoid cache thrashing. Finally, this paper studies the relationship between fairness and throughput in detail. We found that optimizing fairness usually increases throughput, while maximizing throughput does not necessarily improve fairness. Using a set of co-scheduled pairs of benchmarks, on average our algorithms improve fairness by a factor of 4/spl times/, while increasing the throughput by 15%, compared to a nonpartitioned shared cache.

Journal ArticleDOI
TL;DR: It is argued that cryptic genetic variation is pervasive but under-appreciated, recent progress in determining the nature and identity of genes that underlie cryptic genetic effects is highlighted, and future research directions are outlined.
Abstract: Cryptic genetic variation is the dark matter of biology: it is variation that is not normally seen, but that might be an essential source of physiological and evolutionary potential. It is uncovered by environmental or genetic perturbations, and is thought to modify the penetrance of common diseases, the response of livestock and crops to artificial selection and the capacity of populations to respond to the emergence of a potentially advantageous macro-mutation. We argue in this review that cryptic genetic variation is pervasive but under-appreciated, we highlight recent progress in determining the nature and identity of genes that underlie cryptic genetic effects and we outline future research directions.

Proceedings ArticleDOI
25 Oct 2004
TL;DR: This work presents a localization technique based on a single mobile beacon aware of its position, and thus no extra hardware is necessary, and the accuracy is sufficient for most applications.
Abstract: Wireless sensor networks have the potential to become the pervasive sensing (and actuating) technology of the future For many applications, a large number of inexpensive sensors is preferable to a few expensive ones The large number of sensors in a sensor network and most application scenarios preclude hand placement of the sensors Determining the physical location of the sensors after they have been deployed is known as the problem of localization We present a localization technique based on a single mobile beacon aware of its position (eg by being equipped with a GPS receiver) Sensor nodes receiving beacon packets infer proximity constraints to the mobile beacon and use them to construct and maintain position estimates The proposed scheme is radio-frequency based, and thus no extra hardware is necessary The accuracy (on the order of a few meters in most cases) is sufficient for most applications An implementation is used to evaluate the performance of the proposed approach

Journal ArticleDOI
TL;DR: In this paper, base station cooperative processing is explored to address the CCI mitigation problem in downlink multicell multiuser MIMO networks, and is shown to dramatically increase the capacity with strong CCI.
Abstract: Recently, the remarkable capacity potential of multiple-input multiple-output (MIMO) wireless communication systems was unveiled. The predicted enormous capacity gain of MIMO is nonetheless significantly limited by cochannel interference (CCI) in realistic cellular environments. The previously proposed advanced receiver technique improves the system performance at the cost of increased receiver complexity, and the achieved system capacity is still significantly away from the interference-free capacity upper bound, especially in environments with strong CCI. In this paper, base station cooperative processing is explored to address the CCI mitigation problem in downlink multicell multiuser MIMO networks, and is shown to dramatically increase the capacity with strong CCI. Both information-theoretic dirty paper coding approach and several more practical joint transmission schemes are studied with pooled and practical per-base power constraints, respectively. Besides the CCI mitigation potential, other advantages of cooperative processing including the power gain, channel rank/conditioning advantage, and macrodiversity protection are also addressed. The potential of our proposed joint transmission schemes is verified with both heuristic and realistic cellular MIMO settings.

Journal ArticleDOI
TL;DR: These naturally occurring stilbenes, known to be strong antioxidants and to have cancer chemopreventive activities, will add to the purported health benefits derived from the consumption of these small fruits.
Abstract: A study was conducted to determine the presence of resveratrol, pterostilbene, and piceatannol in Vaccinium berries. Samples representing selections and cultivars of 10 species from Mississippi, North Carolina, Oregon, and Canada were analyzed by gas chromatography/mass spectrometry. Resveratrol was found in Vaccinium angustifolium (lowbush blueberry), Vaccinium arboretum (sparkleberry), Vaccinium ashei (rabbiteye blueberry), Vaccinium corymbosum (highbush blueberry), Vaccinium elliottii (Elliott's blueberry), Vaccinium macrocarpon (cranberry), Vaccinium myrtillus (bilberry), Vaccinium stamineum (deerberry), Vaccinium vitis-ideae var. vitis-ideae (lingonberry), and Vaccinium vitis-ideae var. minor (partridgeberry) at levels between 7 and 5884 ng/g dry sample. Lingonberry was found to have the highest content, 5884 ng/g dry sample, comparable to that found in grapes, 6471 ng/g dry sample. Pterostilbene was found in two cultivars of V. ashei and in V. stamineum at levels of 99-520 ng/g dry sample. Piceatannol was found in V. corymbosum and V. stamineum at levels of 138-422 ng/g dry sample. These naturally occurring stilbenes, known to be strong antioxidants and to have cancer chemopreventive activities, will add to the purported health benefits derived from the consumption of these small fruits.

Journal ArticleDOI
TL;DR: A review of the strengths and pitfalls of the Raman technique for the analysis of diamond and diamond films can be found in this article, where some of the latest developments hold the promise of providing a more profound understanding of the outstanding properties of these materials.
Abstract: The optimization of diamond films as valuable engineering materials for a wide variety of applications has required the development of robust methods for their characterization. Of the many methods used, Raman microscopy is perhaps the most valuable because it provides readily distinguishable signatures of each of the different forms of carbon (e.g. diamond, graphite, buckyballs). In addition it is non-destructive, requires little or no specimen preparation, is performed in air and can produce spatially resolved maps of the different forms of carbon within a specimen. This article begins by reviewing the strengths (and some of the pitfalls) of the Raman technique for the analysis of diamond and diamond films and surveys some of the latest developments (for example, surface-enhanced Raman and ultraviolet Raman spectroscopy) which hold the promise of providing a more profound understanding of the outstanding properties of these materials. The remainder of the article is devoted to the uses of Raman spectroscopy in diamond science and technology. Topics covered include using Raman spectroscopy to assess stress, crystalline perfection, phase purity, crystallite size, point defects and doping in diamond and diamond films.