Q1. What are the contributions in this paper?
In this paper, Mahmood et al. reported the crystal structures of new 2D polymeric cadmium ( II ) complexes containing 1,3imidazolidine-2-thione ( Imt ) ligand.
2D polymeric cadmium(II) complexes containing 1,3-imidazolidine-2-thione (Imt) ligand, [Cd(Imt)(H2O)2(SO4)]n and [Cd(Imt)2(N3)2]n
Rashid Mahmood,Saeed Ahmad,Mohammed Fettouhi,Thierry Roisnel,Mazhar Amjad Gilani,Kashif Mehmood,Ghulam Murtaza,Anvarhusein A. Isab +7 more
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TLDR
In this paper, the structural investigation of two polymeric cadmium(II) complexes of imidazolidine-2-thione (Imt) based on sulfate or azide ions was carried out.About:
This article is published in Journal of Molecular Structure.The article was published on 2018-03-15 and is currently open access. It has received 9 citations till now. The article focuses on the topics: Octahedral molecular geometry & Coordination sphere.read more
Figures
Table 1. Crystal data and details of the structure refinement for compounds 1 and 2. 
Figure 6. View of the packing of the 2D networks in compound 2 in the form of a 3D network 
Table 2. Selected bond distances (Å) and bond angles (˚) for compounds 1 and 2 
Figure 4. ORTEP diagram of the molecular structure of compound 2 showing the atomic labeling scheme. Thermal ellipsoids have been drawn t 50% probability level. Symmetry codes: i = x, 1+y, z ; ii = -x+1/2, -y+3/2, 1-z ; iii = 1-x, y, -z+3/2 
Table 3 Hydrogen bond parameters in complexes 1 and 2 (Å, deg)a _______________________________________________________________________ D-H...A d(D-H) d(H...A) d(D...A) ∠(D-H-A) _______________________________________________________________________ (1)
Citations
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Heterocyclic-2-thione derivatives of group 10–12 metals: Coordination versatility, activation of CS (thione) bonds and biochemical potential
TL;DR: A survey of relatively recent coordination compounds of these metals is described with selective heterocyclic thiones, namely, pyridine-2-thione, pyrimidine-two-thiones and purine-6thione as discussed by the authors.
Journal ArticleDOI
Synthesis, S-alkylation, and fungicidal activity of 4-(benzylideneamino)thioglycolurils
Galina A. Gazieva,T. V. Nechaeva,N. N. Kostikova,Natalya V. Sigay,S. A. Serkov,Sergey V. Popkov +5 more
TL;DR: In this article, a series of 1,3-disubstituted 4-benzylideneamino-5thioxohexahydroimidazo[4,5-d]imidazol-2(1H)-ones (thioglycolurils) was synthesized via the reaction of 5,7-disubsubstitized 3-thioxoperhydroIMidazo [4, 5-e]-1,2,4-triazin-6-ones with hydroxy-, alkoxy-, and
Journal ArticleDOI
Synthesis, crystalline structures and photophysical properties of new cadmium iodide complexes with thiocarbamoyl-pyrazoline ligands
Persiely P. Rosa,Guilherme B Laranjeira,Lis R.V. Favarin,Lucas Pizzuti,Amilcar Machulek Junior,Leandro M. C. Pinto,Claudia C. Gatto,Anderson R.L. Caires,Carolina G. Oliveira,Victor M. Deflon,Gleison A. Casagrande +10 more
TL;DR: In this article, new mononuclear cadmium (II) complexes based on thiocarbamoyl-pyrazoline ligands were synthesized and structurally characterized.
Journal ArticleDOI
Synthesis, characterization, DFT calculations and antimicrobial studies of cadmium(II) sulfate complexes of thioureas and 2-mercaptopyridine; X-ray structures of polymeric diaqua(N,N′-dimethylthiourea) sulfatocadmium(II) and bis(2-mercaptopyridine)sulfatocadmium(II)
Saeed Ahmad,Muhammad Saleem,Ivelina Georgieva,Tobias Rüffer,Dieter Schaarschmidt,Heinrich Lang,Ghulam Murtaza,Irshad Hussain,Habib-ur-Rehman,Anvarhusein A. Isab,Muhammad Riaz Malik,Saqib Ali +11 more
TL;DR: In this article, the properties of the Cadmium(II) complexes of thioureas, [Cd(Tu)(SO4)(H2O)2]n (1), [Ccd(Dmtu)2(SO4), H2O 2, H2 O 2 ]n (2) and Mpy 2(Mpy) 2(SO 4 )n (3) were characterized by IR and NMR spectroscopy, and thermal analysis.
Journal ArticleDOI
Synthesis, characterization and in vitro cytotoxicity of Au(I) carbene complexes
Sughra Gulzar,Zeeshan Abid,Raja Shahid Ashraf,Muhammad Sher,Anvarhusein A. Isab,Muhammad Altaf +5 more
TL;DR: In this paper , the authors synthesized four new Au(I)-NHC complexes (1-4) by reacting (1,3-bis(2,6-di-isopropylphenyl)imidazol-2-ylidenegold(I)chloride) (Au(Ipr)Cl) with four different thiones, namely N-(i-propyl)IMidazolidine- 2-thione (i-PrImt), N-(dipropyl)-imidrazolidine (2-THione), 1, 3-Diazinane-2,Diaz, and 1,3 -Diazipane- 2 -thione(Diap), which showed moderate anticancer activities against selected cancer cell lines.
References
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Journal ArticleDOI
Synthesis and Crystal Structures of Cadmium Iodide Complexes of N,N ′-Diethylthiourea and 1,3-Diazinane-2-thione
Saeed Ahmad,Quemars Amir,Ghazala Naz,Atif Fazal,Mohammed Fettouhi,Anvarhusein A. Isab,Tobias Rüffer,Heinrich Lang +7 more
TL;DR: In this article, two cadmium(II) iodide complexes, [Cd(Detu)2I2] (1) and [cd(Diaz)2II] (2) have been prepared and their structures were determined by X-ray crystallography.
Journal ArticleDOI
Dichlorobis[1-methylimidazoline-2(3H)-thione]-cadmium(II)
TL;DR: In this paper, the Cd atom has a distorted tetrahedral coordination geometry, with two Cl− and two monodentate neutral thione ligands bonded through S. There are intra-molecular N−H⋯Cl and inter-molescular N-H⌉S hydrogen bonds, generating centrosymmetric dimers.
Journal ArticleDOI
Structural characterization of dichloridobis(N,N’-dimethylthiourea-S)cadmium(II)
TL;DR: In this article, a cadmium(II) complex, called dichloridobis(N,N’-dimethylthiourea-S)cadmium (II), [Cd(Dmtu)2Cl2] (1), was prepared and its structure was determined by X-ray crystal structure analysis.
Journal ArticleDOI
Structural characterization of a cadmium(II)-sulfato complex, [Cd(N,N′-diethyl thiourea)4(SO4)]
Muhammad Altaf,Helen Stoeckli-Evans,Ghulam Murtaza,Anvarhusein A. Isab,Saeed Ahmad,Muhammad Ashraf Shaheen +5 more
TL;DR: In this article, a cadmium(II) complex, tetrakis(N,N′-diethylthiourea)sulfatocadmium (II), [Cd(Detu)4SO4] (1) is prepared and its crystal structure is determined by X-ray crystallography.
Journal ArticleDOI
Synthesis, characterization, DFT calculations and antibacterial activity of palladium(II) cyanide complexes with thioamides
Saeed Ahmad,Shafqat Nadeem,Aneela Anwar,Abdul Hameed,Syed Ahmed Tirmizi,Wiktor Zierkiewicz,Azhar Abbas,Anvarhusein A. Isab,Mshari A. Alotaibi +8 more
TL;DR: Palladium(II) cyanide complexes of thioamides (or thiones) having the general formula PdL2(CN)2, where L ǫ = Tu, Methylthiourea (Metu), N,N′-Dimethylthiamine (Dmtu), Tetramethylthiusmide (Tmtu, 2-Mercaptopyridine (Mpy) and 2 -Mercaptopyrimidine(Mpm) were prepared by reacting K2[PdCl4] with potassium cyanide and thio