Journal ArticleDOI
A Fast Deposition‐Crystallization Procedure for Highly Efficient Lead Iodide Perovskite Thin‐Film Solar Cells
Manda Xiao,Fuzhi Huang,Wenchao Huang,Yasmina Dkhissi,Ye Zhu,Joanne Etheridge,Angus Gray-Weale,Udo Bach,Udo Bach,Udo Bach,Yi-Bing Cheng,Leone Spiccia +11 more
TLDR
It is reported that flat, uniform thin films of this material can be deposited by a one-step, solvent-induced, fast crystallization method involving spin-coating of a DMF solution of CH3NH3PbI3 followed immediately by exposure to chlorobenzene to induce crystallization.Abstract:
Thin-film photovoltaics based on alkylammonium lead iodide perovskite light absorbers have recently emerged as a promising low-cost solar energy harvesting technology. To date, the perovskite layer in these efficient solar cells has generally been fabricated by either vapor deposition or a two-step sequential deposition process. We report that flat, uniform thin films of this material can be deposited by a one-step, solvent-induced, fast crystallization method involving spin-coating of a DMF solution of CH3NH3PbI3 followed immediately by exposure to chlorobenzene to induce crystallization. Analysis of the devices and films revealed that the perovskite films consist of large crystalline grains with sizes up to microns. Planar heterojunction solar cells constructed with these solution-processed thin films yielded an average power conversion efficiency of 13.9±0.7% and a steady state efficiency of 13% under standard AM 1.5 conditions.read more
Citations
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Journal ArticleDOI
Low trap-state density and long carrier diffusion in organolead trihalide perovskite single crystals
Dong Shi,Valerio Adinolfi,Riccardo Comin,Mingjian Yuan,Erkki Alarousu,Andrei Buin,Yin Chen,Sjoerd Hoogland,Alexander Rothenberger,Khabiboulakh Katsiev,Yaroslav Losovyj,Xin Zhang,Peter A. Dowben,Omar F. Mohammed,Edward H. Sargent,Osman M. Bakr +15 more
TL;DR: An antisolvent vapor-assisted crystallization approach is reported that enables us to create sizable crack-free MAPbX3 single crystals with volumes exceeding 100 cubic millimeters, which enabled a detailed characterization of their optical and charge transport characteristics.
Journal ArticleDOI
High-efficiency solution-processed perovskite solar cells with millimeter-scale grains
Wanyi Nie,Hsinhan Tsai,Reza Asadpour,Jean-Christophe Blancon,Amanda Neukirch,Gautam Gupta,Jared Crochet,Manish Chhowalla,Sergei Tretiak,Muhammad A. Alam,Hsing-Lin Wang,Aditya D. Mohite +11 more
TL;DR: A solution-based hot-casting technique is demonstrated to grow continuous, pinhole-free thin films of organometallic perovskites with millimeter-scale crystalline grains that are applicable to several other material systems plagued by polydispersity, defects, and grain boundary recombination in solution-processed thin films.
Journal ArticleDOI
Metal-halide perovskites for photovoltaic and light-emitting devices
TL;DR: The broad tunability and fabrication methods of these materials, the current understanding of the operation of state-of-the-art solar cells and the properties that have delivered light-emitting diodes and lasers are described.
Journal ArticleDOI
Overcoming the electroluminescence efficiency limitations of perovskite light-emitting diodes.
Himchan Cho,Su Hun Jeong,Min-Ho Park,Young-Hoon Kim,Christoph Wolf,Chang-Lyoul Lee,Jin Hyuck Heo,Aditya Sadhanala,NoSoung Myoung,Seunghyup Yoo,Sang Hyuk Im,Richard H. Friend,Tae-Woo Lee +12 more
TL;DR: Efficient organic-inorganic perovskite light-emitting diodes were made with nanograin crystals that lack metallic lead, which helped to confine excitons and avoid their quenching.
Journal ArticleDOI
Improved air stability of perovskite solar cells via solution-processed metal oxide transport layers
Jingbi You,Lei Meng,Tze-Bin Song,Tzung-Fang Guo,Yang Yang,Wei-Hsuan Chang,Ziruo Hong,Huajun Chen,Huanping Zhou,Qi Chen,Yongsheng Liu,Nicholas De Marco +11 more
TL;DR: A solution-processed lead halide perovskite solar cell that has p-type NiO(x) and n-type ZnO nanoparticles as hole and electron transport layers, respectively, and shows improved stability against water and oxygen degradation when compared with devices with organic charge transport layers is reported.
References
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Journal ArticleDOI
Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells
TL;DR: Two organolead halide perovskite nanocrystals were found to efficiently sensitize TiO(2) for visible-light conversion in photoelectrochemical cells, which exhibit strong band-gap absorptions as semiconductors.
Journal ArticleDOI
Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites
Michael M. Lee,Joël Teuscher,Tsutomu Miyasaka,Takurou N. Murakami,Takurou N. Murakami,Henry J. Snaith +5 more
TL;DR: A low-cost, solution-processable solar cell, based on a highly crystalline perovskite absorber with intense visible to near-infrared absorptivity, that has a power conversion efficiency of 10.9% in a single-junction device under simulated full sunlight is reported.
Journal ArticleDOI
Sequential deposition as a route to high-performance perovskite-sensitized solar cells
Julian Burschka,Norman Pellet,Norman Pellet,Soo-Jin Moon,Robin Humphry-Baker,Peng Gao,Mohammad Khaja Nazeeruddin,Michael Grätzel +7 more
TL;DR: A sequential deposition method for the formation of the perovskite pigment within the porous metal oxide film that greatly increases the reproducibility of their performance and allows the fabrication of solid-state mesoscopic solar cells with unprecedented power conversion efficiencies and high stability.
Journal ArticleDOI
Plasmonics for improved photovoltaic devices
Harry A. Atwater,Albert Polman +1 more
TL;DR: Recent advances at the intersection of plasmonics and photovoltaics are surveyed and an outlook on the future of solar cells based on these principles is offered.
Journal ArticleDOI
Efficient planar heterojunction perovskite solar cells by vapour deposition
TL;DR: It is shown that perovskite absorbers can function at the highest efficiencies in simplified device architectures, without the need for complex nanostructures.