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Applications of lignin-derived catalysts for green synthesis

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TLDR
In this paper, the application of lignin-derived catalyst for green organic synthesis over latest two decades and aims to present a renewable alternative for conventional catalyst for future industry application.
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This article is published in Green Energy & Environment.The article was published on 2019-07-01 and is currently open access. It has received 81 citations till now. The article focuses on the topics: Catalysis & Knoevenagel condensation.

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Catalytic Stereoselective Conversion of Biomass-Derived 4′-Methoxypropiophenone to Trans-Anethole with a Bifunctional and Recyclable Hf-Based Polymeric Nanocatalyst

TL;DR: In this article, an acid-base bifunctional polymeric material (PhP-Hf (1:1.5)) composed of hafnium and phenylphosphonate in a molar ratio of 1.5 for catalytic conversion of biomass-derived 4-methoxypropiophenone (4-MOPP) to AN via cascade Meerwein-Pondorf-Verley (MPV) reduction and dehydration reactions in a single pot.
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Superficial properties of activated carbon fiber catalysts produced by green synthesis and their application in water purification

TL;DR: It was found that the two synthesis processes modified the properties of the support and that the distribution of the particles of the metallic phase was of the nanometric order, being these particles found predominantly at the support surface.
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A novel and robust heterogeneous Cu catalyst using modified lignosulfonate as support for the synthesis of nitrogen-containing heterocycles.

TL;DR: This catalyst exhibited excellent catalytic activity in the synthesis of nitrogen-containing heterocycles such as tricyclic indoles bearing 3,4-fused seven-membered rings, 2‑arylpyridines, aminonaphthalenes and 3-phenylisoquinolines.
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Formic acid-facilitated hydrothermal pretreatment of raw biomass for co-producing xylo-oligosaccharides, glucose, and lignin

TL;DR: In this article , a formic acid-facilitated hydrothermal pretreatment of bamboo was investegated to increase the yield of xylo-oligosaccharides by controlling the severity factor (SF) and formic acids concentration.
References
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Journal ArticleDOI

The Catalytic Valorization of Lignin for the Production of Renewable Chemicals

TL;DR: Biomass is an important feedstock for the renewable production of fuels, chemicals, and energy, and it recently surpassed hydroelectric energy as the largest domestic source of renewable energy.
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Technology development for the production of biobased products from biorefinery carbohydrates—the US Department of Energy’s “Top 10” revisited

TL;DR: An updated evaluation of potential target structures using similar selection methodology, and an overview of the technology developments that led to the inclusion of a given compound are presented.
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Lignin valorization: improving lignin processing in the biorefinery.

TL;DR: Recent developments in genetic engineering, enhanced extraction methods, and a deeper understanding of the structure of lignin are yielding promising opportunities for efficient conversion of this renewable resource to carbon fibers, polymers, commodity chemicals, and fuels.
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Ionic liquids. Green solvents for the future

TL;DR: In this paper, it has been shown that Ionic liquids, being composed entirely of ions, are green solvents, and that a wide range of chemical reactions can be performed in them.
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Palladium-Catalyzed Suzuki-Miyaura Cross-coupling Reactions Employing Dialkylbiaryl Phosphine Ligands

TL;DR: An overview of the use and impact of dialkylbiarylphosphine ligands in the Suzuki-Miyaura cross-coupling reaction and the utility of these ligands has been successfully demonstrated in a wide number of synthetic applications, including industrially relevant processes.
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