Journal ArticleDOI
Determination of crystallite size and lattice distortions through X-ray diffraction line profile analysis
TLDR
In this paper, a detailed analysis of line profiles in terms of Fourier coefficients is presented, and the subsequent steps of measurement, data correction and evaluation are elucidated; alternatives are indicated; and it is expected that line profile analysis will become an automated routine-like analytical method soon, since the tools are available: non-expensive computers, error calculations and commercially available software.Abstract:
Methods for the determination of crystallite size and lattice strain from X-ray diffraction line broadening are discussed. The subsequent steps of measurement, data correction and evaluation are elucidated; alternatives are indicated. Emphasis is laid on the rigorous analysis of line profiles in terms of Fourier coefficients. For the analysis in terms of integral breadth and full width at half maximum a powerful method exists which adopts a Voigt function for describing the shape of the profiles. Size broadening, strain broadening and single-line methods are commented. A practical example is given of the influence of a non-ideal standard line profile and of different background estimates when a Fourier deconvolution and a Warren-Averbach size-strain analysis are performed. It is expected that line profile analysis will become an automated routine-like analytical method soon, since the tools are available: non-expensive computers, error calculations and commercially available software.read more
Citations
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Journal ArticleDOI
Ductile CoCrFeNiMox high entropy alloys strengthened by hard intermetallic phases
W.H. Liu,Zhaoping Lu,Junyang He,Junhua Luan,Zhi-Tai Wang,Bin Liu,Yong Liu,Mingwei Chen,C.T. Liu +8 more
TL;DR: In this article, the authors showed that the precipitation of hard σ and μ intermetallic compounds tremendously strengthened the CoCrFeNiMo 0.3 HEA but without causing a serious embrittlement.
Journal ArticleDOI
X-ray diffraction analysis by Williamson-Hall, Halder-Wagner and size-strain plot methods of CdSe nanoparticles- a comparative study
TL;DR: In this article, the average particle size has been determined from Williamson-Hall, Size-Strain, Halder-Wagner Methods and compared with HR-TEM, AFM, and SEM analysis.
Journal ArticleDOI
Effect of sulphuric acid treatment on the physico-chemical characteristics of kaolin clay
TL;DR: In this article, the physicico-chemical characteristics of acid-leached kaolinite clay were studied by XRF, XRD, FTIR, TGA, DTA, SEM and N 2 adsorption techniques.
Journal ArticleDOI
The “state of the art” of the diffraction analysis of crystallite size and lattice strain.
TL;DR: In this article, the authors address both old, but "renovated" methods and new methods for diffraction line-profile analysis, focusing on distinct anisotropic linebroadening effects, as due to the type, orientation and distribution of dislocations and minute compositional variation.
Journal ArticleDOI
Record mobility in transparent p-type tin monoxide films and devices by phase engineering.
J. A. Caraveo-Frescas,Pradipta K. Nayak,Hala Al-Jawhari,Danilo Bianchi Granato,Udo Schwingenschlögl,Husam N. Alshareef +5 more
TL;DR: It is shown that phase-pure SnO is not necessarily the highest mobility phase; instead, well-controlled amounts of residual metallic tin are shown to substantially increase the hole mobility and this high mobility is realized by careful phase engineering.
References
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Book
International tables for X-ray crystallography
Norman Fordyce McKerron Henry,Lonsdale, Kathleen, Dame,John S. Kasper,Caroline H. MacGillavry,Gerard D. Rieck,James A. Ibers,Walter C. Hamilton +6 more
Journal ArticleDOI
Scherrer after sixty years: a survey and some new results in the determination of crystallite size
J. I. Langford,A. J. C. Wilson +1 more
TL;DR: In this article, the Scherrer constants of simple regular shapes have been determined for all low-angle reflections (h2 + k2 + l2 ≤ 100) for four measures of breadth.
Journal ArticleDOI
The Effect of Cold‐Work Distortion on X‐Ray Patterns
B. E. Warren,B. L. Averbach +1 more
TL;DR: In this article, a cosine Fourier series and a set of An coefficients determined by measuring several orders of a given plane is used to obtain a distribution function of the strains directly from a Fourier transform of the An coefficients.