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Effects of confinement on freezing and melting.

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TLDR
Both simple and more complex adsorbates that are confined in various environments (slit or cylindrical pores and also disordered porous materials) are considered and how confinement affects the glass transition is addressed.
Abstract
We present a review of experimental, theoretical, and molecular simulation studies of confinement effects on freezing and melting We consider both simple and more complex adsorbates that are confined in various environments (slit or cylindrical pores and also disordered porous materials) The most commonly used molecular simulation, theoretical and experimental methods are first presented We also provide a brief description of the most widely used porous materials The current state of knowledge on the effects of confinement on structure and freezing temperature, and the appearance of new surface-driven and confinement-driven phases are then discussed We also address how confinement affects the glass transition

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David J. Thouless
- 01 Apr 1972 - 
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Nanoconfined Ionic Liquids

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References
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Journal ArticleDOI

First-principles order-parameter theory of freezing

TL;DR: In this article, a first-principles order-parameter theory of the fluid-solid transition is presented, where the thermodynamic potential of the system is computed as a function of order parameters.
Journal ArticleDOI

Two-dimensional melting

TL;DR: A review of the current status of research into the problem of two-dimensional melting, with an emphasis on computer simulations, is given in this article, where an attempt is made to point out unresolved issues pertaining to this fascinating and still open question.
Journal ArticleDOI

Characterization of Porous Solids

TL;DR: The analysis of pore structure is complicated by the wide range in pore sizes observed, from molecular ( 1 mm) dimensions, complex pore shapes and connectivities, chemical and physical heterogeneities, and pore structures changes that can occur during characterization as discussed by the authors.
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The Direct Measurement of Normal and Retarded van der Waals Forces

TL;DR: In this article, a direct measurement of the forces in air between two cylindrical sheets of mica arranged with their axes mutually at right angles is made using multiple beam interferometry using fringes of equal chromatic order.
Book

Carbon Nanotubes and Related Structures: New Materials for the Twenty-first Century

TL;DR: The physics of nanotubes and their properties are discussed in this paper, where the ultimate carbon fibre is described as "curved crystals, inorganic fullerenes and nanorods".
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