Journal ArticleDOI
Effects of confinement on freezing and melting.
Christiane Alba-Simionesco,Benoit Coasne,Gilberte Dosseh,G. Dudziak,Keith E. Gubbins,Ravi Radhakrishnan,Malgorzata Sliwinska-Bartkowiak +6 more
TLDR
Both simple and more complex adsorbates that are confined in various environments (slit or cylindrical pores and also disordered porous materials) are considered and how confinement affects the glass transition is addressed.Abstract:
We present a review of experimental, theoretical, and molecular simulation studies of confinement effects on freezing and melting We consider both simple and more complex adsorbates that are confined in various environments (slit or cylindrical pores and also disordered porous materials) The most commonly used molecular simulation, theoretical and experimental methods are first presented We also provide a brief description of the most widely used porous materials The current state of knowledge on the effects of confinement on structure and freezing temperature, and the appearance of new surface-driven and confinement-driven phases are then discussed We also address how confinement affects the glass transitionread more
Citations
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Complex plasmas: An interdisciplinary research field
TL;DR: Complex (dusty) plasmas are composed of a weakly ionized gas and charged microparticles and represent the plasma state of soft matter as discussed by the authors, and they can be easily manipulated in different ways, also at the level of individual particles.
Journal ArticleDOI
The Physics of the Colloidal Glass Transition
Gary L. Hunter,Eric R. Weeks +1 more
TL;DR: A review of the current state of understanding of the colloidal glass transition, with an emphasis on experimental observations, is given in this paper, where the authors describe features of colloidal systems near and in glassy states, including increases in viscosity and relaxation times, dynamical heterogeneity and ageing.
Journal ArticleDOI
Introduction to Phase Transitions and Critical Phenomena
TL;DR: There has been a lot of experimental and theoretical work on the nature of critical phenomena in the neighbourhood of second order phase transitions as discussed by the authors, but it has not been easy to get a good overall view of this work without digging through the rather complex original literature, although there are some good review articles covering particular aspects of the work.
Journal ArticleDOI
Nanoconfined Ionic Liquids
TL;DR: A comprehensive review of nanoconfined ILs, a new class of composites with the intrinsic chemistries of ILs and the original functions of solid matrices, highlighting the potential applications in diverse fields, including catalysis, gas capture and separation, ionogels, supercapacitors, carbonization, and lubrication.
References
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Journal ArticleDOI
Defects and Geometry in Condensed Matter Physics
TL;DR: In this article, the key role played by thermally excited defects such as vortices, disclinations, dislocations, vacancies and interstitials in the physics of crystals, superfluids, superconductors, liquid crystals and polymer arrays is described.
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Modified weighted-density-functional theory of nonuniform classical liquids
Alan R. Denton,N. W. Ashcroft +1 more
TL;DR: It is concluded that in its new formulation the WDA is now just as simple to implement as the widely used Ramakrishnan-Yussouff' theory.
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Phase diagram of hard spheres confined between two parallel plates
Matthias Schmidt,Hartmut Löwen +1 more
TL;DR: In this article, a hard sphere system confined between two parallel hard plates is investigated theoretically using extensive Monte Carlo computer simulations, and the phase diagram is calculated for the whole range of densities and plate separations ranging from one to two particle diameters.
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Reduction of the glass transition temperature in polymer films: a molecular-dynamics study.
TL;DR: Results of molecular-dynamics simulations for a nonentangled polymer melt confined between two completely smooth and repulsive walls, interacting with inner particles via the potential U(wall)=(sigma/z)(9), are in qualitative agreement with that of the glass transition temperature observed in some experiments on supported polymer films.