Journal ArticleDOI
Energy related CO2 conversion and utilization: Advanced materials/nanomaterials, reaction mechanisms and technologies
Yun Zheng,Wenqiang Zhang,Yifeng Li,Jing Chen,Bo Yu,Jianchen Wang,Lei Zhang,Lei Zhang,Jiujun Zhang,Jiujun Zhang +9 more
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TLDR
In this paper, a comprehensive overview of CO 2 conversion using advanced materials/nanomaterials and technologies for the production of useful fuels/chemicals is provided, and the economic feasibility for CO 2 utilization is analyzed with cases of various chemicals/fuels.Citations
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Correction: Metal chalcogenide-associated catalysts enabling CO2 electroreduction to produce low-carbon fuels for energy storage and emission reduction: catalyst structure, morphology, performance, and mechanism
Xiaolin Shao,Xurui Zhang,Yuyu Liu,Jinli Qiao,Xiao-Dong Zhou,Nengneng Xu,Jamie L. Malcombe,Jin Yi,Jiujun Zhang +8 more
TL;DR: In this paper, the recent advances in metal chalcogenide-associated materials for ERCO2 catalysis are reviewed in terms of their synthesis, characterization, functional mechanisms, and catalytic performance/optimization.
Journal ArticleDOI
Kinetic study of CO2 hydrogenation on Ru/ YSZ catalyst using a monolithic electropromoted reactor (MEPR)
TL;DR: In this paper , the authors investigated the kinetic mechanism of electrochemical promotion of CO2 hydrogenation using a scaled up, monolithic electropromoted reactor (MEPR) loaded with nine parallelly connected Ru/YSZ/Au electrochemical cells.
Journal ArticleDOI
Interfacial Ni active sites strike solid solutional counterpart in CO2 hydrogenation
Ákos Szamosvölgyi,T. Rajkumar,András Sápi,Imre Szenti,Marietta Ábel,Juan Gómez-Pérez,Kornélia Baán,Zsolt Fogarassy,E. Dodony,Béla Pécz,Seema Garg,János Kiss,Ákos Kukovecz,Zoltán Kónya +13 more
TL;DR: In this paper , a 4 mol% NiO/CeO2 interfacial oxide where CeO2 supports NiO nanoparticles was produced by wet impregnation method and a Ce0.96Ni0.04O2 mixed oxide was obtained by co-precipitation of Ce3+ and Ni2+ ions.
Journal ArticleDOI
High reversible cycling performance of carbon dioxide electrolysis by flat-tube solid oxide cell
TL;DR: In this paper , the performance and stability of flat-tube solid oxide cells during periodic cycles of CO2 electrolysis and hydrogen fuel discharge were studied, and the cell underwent 26 reversible cycles of operation for 624 h. Compared with long-term constant current electrolysis, the alternate operation of charge and discharge used in this study is more typical of actual application conditions.
Journal ArticleDOI
Revealing the Surface Chemistry for CO2 Hydrogenation on Cu/CeO2–x Using Near-Ambient-Pressure X-ray Photoelectron Spectroscopy
Mo Li,Mo Li,Thi Ha My Pham,Thi Ha My Pham,Emad Oveisi,Youngdon Ko,Youngdon Ko,Wen Luo,Wen Luo,Wen Luo,Andreas Züttel,Andreas Züttel +11 more
TL;DR: In this article, the authors have shown that CeO2-supported Cu catalysts have shown high activity and selectivity for the hydrogenation of CO2 to CO2, which is an attractive route for CO2 recycling.
References
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TL;DR: In this article, the first law of thermodynamics and the third law of Nernst heat theorem are used to construct tables of thermochemical data of pure substances, which are then used for thermodynamic calculations.
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A perovskite oxide optimized for oxygen evolution catalysis from molecular orbital principles.
TL;DR: The high activity of BSCF was predicted from a design principle established by systematic examination of more than 10 transition metal oxides, which showed that the intrinsic OER activity exhibits a volcano-shaped dependence on the occupancy of the 3d electron with an eg symmetry of surface transition metal cations in an oxide.
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TL;DR: Reaction Mechanism, Synthesis of Urea and Urethane Derivatives, and Alcohol Homologation 2382 10.1.
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Recent advances in catalytic hydrogenation of carbon dioxide
TL;DR: A critical review of recent developments in hydrogenation reaction, with emphases on catalytic reactivity, reactor innovation, and reaction mechanism, provides an overview regarding the challenges and opportunities for future research in the field.
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How copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels
TL;DR: Density functional theory calculations explain copper's unique ability to convert CO2 into hydrocarbons, which may open up (photo-)electrochemical routes to fuels as mentioned in this paper, which may lead to new energy sources.